About: ELECTROCHEMICAL REDUCTION OF DODECYLPYRIDINIUM BROMIDE IN APROTIC SOLVENTS: MECHANISTIC STUDIES

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Reduction mechanism of 1-dodecylpyridin-1-ium bromide (DPBr) in dimethylsulfoxide has been studied on mercury electrode. Based on the classical polarographic methods as well as on the use of AC techniques it was shown that DPBr is reduced in a reversible one electron transfer step followed by dimerization of the corresponding radical species. Reduction process is accompanied by the adsorption phenomena even in the non-aqueous solvents. Possible modes of DPBr adsorption have been studied by the ex situ scanning tunnelling microscopy (STM) imaging of these molecules on highly oriented pyrolytic graphite. Reduction mechanism of 1-dodecylpyridin-1-ium bromide (DPBr) in dimethylsulfoxide has been studied on mercury electrode. Based on the classical polarographic methods as well as on the use of AC techniques it was shown that DPBr is reduced in a reversible one electron transfer step followed by dimerization of the corresponding radical species. Reduction process is accompanied by the adsorption phenomena even in the non-aqueous solvents. Possible modes of DPBr adsorption have been studied by the ex situ scanning tunnelling microscopy (STM) imaging of these molecules on highly oriented pyrolytic graphite. (en)
Title	ELECTROCHEMICAL REDUCTION OF DODECYLPYRIDINIUM BROMIDE IN APROTIC SOLVENTS: MECHANISTIC STUDIES ELECTROCHEMICAL REDUCTION OF DODECYLPYRIDINIUM BROMIDE IN APROTIC SOLVENTS: MECHANISTIC STUDIES (en)
skos:prefLabel	ELECTROCHEMICAL REDUCTION OF DODECYLPYRIDINIUM BROMIDE IN APROTIC SOLVENTS: MECHANISTIC STUDIES ELECTROCHEMICAL REDUCTION OF DODECYLPYRIDINIUM BROMIDE IN APROTIC SOLVENTS: MECHANISTIC STUDIES (en)
skos:notation	RIV/61388955:_____/11:00372477!RIV12-GA0-61388955
http://linked.open...avai/predkladatel	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/08/1157), P(GA203/09/0705), P(IAA400400802), P(MEB041006), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika	12
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Pospíšil, Lubomír Sokolová, Romana Hromadová, Magdaléna Kolivoška, Viliam
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	197044
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/11:00372477
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	spectroelectrochemistry; dodecylpyridinium bromide; mechanistic studies (en)
http://linked.open.../riv/klicoveSlovo	dodecylpyridinium bromide mechanistic studies spectroelectrochemistry
http://linked.open...odStatuVydavatele	CZ - Česká republika
http://linked.open...ontrolniKodProRIV	[BAAE2BE0B3A8]
http://linked.open...i/riv/nazevZdroje	Collection of Czechoslovak Chemical Communications
http://linked.open...in/vavai/riv/obor	CG
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...vavai/riv/projekt	Transfer of charge in single and assembled molecules Tailoring the lock and key motifs in novel low-dimensional structures at electrified interface Cationic redox catalysis and its role in the observation of electrochemical oscillatory phenomena. Electron transfer in new materials for molecular electronics
http://linked.open...UplatneniVysledku	2011
http://linked.open...v/svazekPeriodika	76
http://linked.open...iv/tvurceVysledku	Hromadová, Magdaléna Kolivoška, Viliam Pospíšil, Lubomír Sokolová, Romana
http://linked.open...ain/vavai/riv/wos	000299816100030
http://linked.open...n/vavai/riv/zamer	Struktura, reaktivita a dynamika molekulárních a biomolekulárních systémů: teorie, experiment, aplikace
issn	0010-0765
number of pages	14 (xsd:int)
http://bibframe.org/vocab/doi	10.1135/cccc2011154
is http://linked.open...avai/riv/vysledek of	ELECTROCHEMICAL REDUCTION OF DODECYLPYRIDINIUM BROMIDE IN APROTIC SOLVENTS: MECHANISTIC STUDIES ELECTROCHEMICAL REDUCTION OF DODECYLPYRIDINIUM BROMIDE IN APROTIC SOLVENTS: MECHANISTIC STUDIES

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