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rdf:type
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Description
| - Ion and electron transfer reactions at the interface between a redox-active ionic liquid (IL), (ferrocenylmethyl)dodecyldimethylammonium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (FcMDDATFPB), and water were investigated by cyclic voltammetry (CV) using the FcMDDATFPB membrane cell. The redox-active IL was shown to exhibit the same ion selectivity as the structurally similar but redox-inactive tridodecylmethylammonium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate. Ion transfer potentials evaluated from CV measurements allowed establishing the scale of absolute potential differences for the interfacial oxidation of FcMDDA+ with the aqueous redox species including IrCl62, Fe(CN)63, Mo(CN)83, ICl2 or IBr2. In order to rationalize experimental data, the theory of CV was developed for an electron transfer at one membrane interface that is coupled with the ion transfer at the other membrane interface.
- Ion and electron transfer reactions at the interface between a redox-active ionic liquid (IL), (ferrocenylmethyl)dodecyldimethylammonium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (FcMDDATFPB), and water were investigated by cyclic voltammetry (CV) using the FcMDDATFPB membrane cell. The redox-active IL was shown to exhibit the same ion selectivity as the structurally similar but redox-inactive tridodecylmethylammonium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate. Ion transfer potentials evaluated from CV measurements allowed establishing the scale of absolute potential differences for the interfacial oxidation of FcMDDA+ with the aqueous redox species including IrCl62, Fe(CN)63, Mo(CN)83, ICl2 or IBr2. In order to rationalize experimental data, the theory of CV was developed for an electron transfer at one membrane interface that is coupled with the ion transfer at the other membrane interface. (en)
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Title
| - Thermodynamic aspects of the electron transfer across the interface between water and a hydrophobic redox-active ionic liquid
- Thermodynamic aspects of the electron transfer across the interface between water and a hydrophobic redox-active ionic liquid (en)
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skos:prefLabel
| - Thermodynamic aspects of the electron transfer across the interface between water and a hydrophobic redox-active ionic liquid
- Thermodynamic aspects of the electron transfer across the interface between water and a hydrophobic redox-active ionic liquid (en)
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skos:notation
| - RIV/61388955:_____/11:00367631!RIV12-GA0-61388955
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http://linked.open...avai/predkladatel
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(GAP206/10/1231), P(GAP206/11/0707), Z(AV0Z40400503)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61388955:_____/11:00367631
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - redox-active ionic liquid; membrane; cyclic voltammetry (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - GB - Spojené království Velké Británie a Severního Irska
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Langmaier, Jan
- Samec, Zdeněk
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http://linked.open...ain/vavai/riv/wos
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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http://bibframe.org/vocab/doi
| - 10.1016/j.electacta.2011.10.003
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is http://linked.open...avai/riv/vysledek
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