About: Copper(I) Chelation by Tetradentate NSSN Donor Ligands: Reversible Oxidation but no Oxygenation

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The copper(I) complexes [Cu(L(4))](ClO(4)), L(4) = 1,6-bis(N-methyl-1H-benzimidazol-2-yl)-2,5-dithiahexane (bmbdh) or 1,7-bis(N-methyl-1H-benzimidazol-2-yl)-2,6-dithiaheptane (bmdhp) were obtained and investigated through structure analysis (bmdhp compounds), cyclic voltammetry, UV/Vis/NIR and EPR spectroelectrochemistry. Structure comparison of the complexes [Cu(bmdhp)](ClO(4)) (1) and [Cu(bmdhp)](SO(3)CF(3)) (2) with the previously reported [Cu(I)(bdhp)(H(2)O)](PF(6))(0.66)(BF(4))(0.34) (4), bdhp = 1,7-bis(1H-benzimidazol-2-yl)-2,6-dithiaheptane, with the related [Cu(I)(mmb)(2)](BF(4)) (5), mmb = 1-methyl-2-methylthiomethyl-1H-benzimidazole, with the oxidised [Cu(II)(bmdhp)(H(2)O)](ClO(4))(2) (7), and with the zinc(II) species [Zn(bmbdh)(H(2)O)(SO(3)CF(3))](SO(3)CF(3)) (8) and {[Zn(mu-bmdhp)(H(2)O)(SO(3)CF(3))](2)}(SO(3)CF(3)) (9) reveal a variety of coordination numbers, L(4) ligand coordination modes, M-N bond lengths and especially N-M-N angles... The copper(I) complexes [Cu(L(4))](ClO(4)), L(4) = 1,6-bis(N-methyl-1H-benzimidazol-2-yl)-2,5-dithiahexane (bmbdh) or 1,7-bis(N-methyl-1H-benzimidazol-2-yl)-2,6-dithiaheptane (bmdhp) were obtained and investigated through structure analysis (bmdhp compounds), cyclic voltammetry, UV/Vis/NIR and EPR spectroelectrochemistry. Structure comparison of the complexes [Cu(bmdhp)](ClO(4)) (1) and [Cu(bmdhp)](SO(3)CF(3)) (2) with the previously reported [Cu(I)(bdhp)(H(2)O)](PF(6))(0.66)(BF(4))(0.34) (4), bdhp = 1,7-bis(1H-benzimidazol-2-yl)-2,6-dithiaheptane, with the related [Cu(I)(mmb)(2)](BF(4)) (5), mmb = 1-methyl-2-methylthiomethyl-1H-benzimidazole, with the oxidised [Cu(II)(bmdhp)(H(2)O)](ClO(4))(2) (7), and with the zinc(II) species [Zn(bmbdh)(H(2)O)(SO(3)CF(3))](SO(3)CF(3)) (8) and {[Zn(mu-bmdhp)(H(2)O)(SO(3)CF(3))](2)}(SO(3)CF(3)) (9) reveal a variety of coordination numbers, L(4) ligand coordination modes, M-N bond lengths and especially N-M-N angles... (en)
Title	Copper(I) Chelation by Tetradentate NSSN Donor Ligands: Reversible Oxidation but no Oxygenation Copper(I) Chelation by Tetradentate NSSN Donor Ligands: Reversible Oxidation but no Oxygenation (en)
skos:prefLabel	Copper(I) Chelation by Tetradentate NSSN Donor Ligands: Reversible Oxidation but no Oxygenation Copper(I) Chelation by Tetradentate NSSN Donor Ligands: Reversible Oxidation but no Oxygenation (en)
skos:notation	RIV/61388955:_____/11:00361650!RIV12-GA0-61388955
http://linked.open...avai/predkladatel	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/09/0705), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika	7-8
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Fiedler, Jan
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	191996
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/11:00361650
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	benzimidazole ligands; coordination geometry; copper (en)
http://linked.open.../riv/klicoveSlovo	benzimidazole ligands coordination geometry copper
http://linked.open...odStatuVydavatele	DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV	[A48C6641759F]
http://linked.open...i/riv/nazevZdroje	Zeitschrift für anorganische und allgemeine Chemie
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...vavai/riv/projekt	Transfer of charge in single and assembled molecules
http://linked.open...UplatneniVysledku	2011
http://linked.open...v/svazekPeriodika	637
http://linked.open...iv/tvurceVysledku	Fiedler, Jan Kaim, W. Manzur, J. Sarkar, B. Schnödt, J. Sieger, M. Su, Ch. Y.
http://linked.open...ain/vavai/riv/wos	000292334400020
http://linked.open...n/vavai/riv/zamer	Struktura, reaktivita a dynamika molekulárních a biomolekulárních systémů: teorie, experiment, aplikace
issn	0044-2313
number of pages	5 (xsd:int)
http://bibframe.org/vocab/doi	10.1002/zaac.201100026
is http://linked.open...avai/riv/vysledek of	Copper(I) Chelation by Tetradentate NSSN Donor Ligands: Reversible Oxidation but no Oxygenation Copper(I) Chelation by Tetradentate NSSN Donor Ligands: Reversible Oxidation but no Oxygenation

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