About: Fine tuning of the catalytic effect of a metal-free porphyrin on the homogeneous oxygen reduction

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About: Fine tuning of the catalytic effect of a metal-free porphyrin on the homogeneous oxygen reduction Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The catalytic effect of tetraphenylporphyrin on the oxygen reduction with ferrocene in 1,2-dichloroethane can be finely tuned by varying the molar ratio of the acid to the catalyst present in the solution. The mechanism involves binding of molecular oxygen to the protonated free porphyrin base, in competition with ion pairing between the protonated base and the acid anion present. The catalytic effect of tetraphenylporphyrin on the oxygen reduction with ferrocene in 1,2-dichloroethane can be finely tuned by varying the molar ratio of the acid to the catalyst present in the solution. The mechanism involves binding of molecular oxygen to the protonated free porphyrin base, in competition with ion pairing between the protonated base and the acid anion present. (en)
Title	Fine tuning of the catalytic effect of a metal-free porphyrin on the homogeneous oxygen reduction Fine tuning of the catalytic effect of a metal-free porphyrin on the homogeneous oxygen reduction (en)
skos:prefLabel	Fine tuning of the catalytic effect of a metal-free porphyrin on the homogeneous oxygen reduction Fine tuning of the catalytic effect of a metal-free porphyrin on the homogeneous oxygen reduction (en)
skos:notation	RIV/61388955:_____/11:00359151!RIV12-GA0-61388955
http://linked.open...avai/predkladatel	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GAP208/11/0697), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika	19
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Samec, Zdeněk Langmaier, Jan Záliš, Stanislav Šebera, Jakub Trojánek, Antonín
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	199778
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/11:00359151
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	porphyrins; catalytic effects (en)
http://linked.open.../riv/klicoveSlovo	catalytic effects porphyrins
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[DF6778A522A1]
http://linked.open...i/riv/nazevZdroje	Chemical Communications
http://linked.open...in/vavai/riv/obor	CG
http://linked.open...ichTvurcuVysledku	5 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...vavai/riv/projekt	Catalysis of the oxygen reduction by metal-free porphyrins at the electrochemically polarized liquid-liquid interfaces
http://linked.open...UplatneniVysledku	2011
http://linked.open...v/svazekPeriodika	47
http://linked.open...iv/tvurceVysledku	Langmaier, Jan Záliš, Stanislav Šebera, Jakub Girault, H. H. Samec, Zdeněk Barbe, J.-M. Trojánek, Antonín
http://linked.open...ain/vavai/riv/wos	000289899600013
http://linked.open...n/vavai/riv/zamer	Struktura, reaktivita a dynamika molekulárních a biomolekulárních systémů: teorie, experiment, aplikace
issn	1359-7345
number of pages	3 (xsd:int)
http://bibframe.org/vocab/doi	10.1039/C1CC11075F
is http://linked.open...avai/riv/vysledek of	Fine tuning of the catalytic effect of a metal-free porphyrin on the homogeneous oxygen reduction Fine tuning of the catalytic effect of a metal-free porphyrin on the homogeneous oxygen reduction

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