About: Effect of dissolved ozone or ferric ions on photodegradation of thiacloprid in presence of different TiO2 catalysts     Goto   Sponge   NotDistinct   Permalink

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  • Combining TiO2 photocatalysis with inorganic oxidants (such as O-3 and H2O2) or transition metal ions (Fe3+, Cu2+ and Ag+) often leads to a synergic effect. Electron transfer between TiO2 and the oxidant is usually involved. Accordingly, the degree of synergy could be influenced by TiO2 surface area. With this in mind, the disappearance of thiacloprid, a neonicotinoid insecticide, was studied applying various photochemical AOPs and different TiO2 photocatalysts. In photocatalytic ozonation experiments, synergic effect of three different TiO2 photocatalysts was quantified. Higher surface area resulted in a more pronounced synergic effect but an increasing amount of TiO2 did not influence the degree of the synergy. This supports the theory that the synergy is a consequence of adsorption of ozone on the TiO2 surface. No synergy was observed in photocatalytic degradation of thiacloprid in the presence of dissolved iron(III) species performed under varied experimental conditions.
  • Combining TiO2 photocatalysis with inorganic oxidants (such as O-3 and H2O2) or transition metal ions (Fe3+, Cu2+ and Ag+) often leads to a synergic effect. Electron transfer between TiO2 and the oxidant is usually involved. Accordingly, the degree of synergy could be influenced by TiO2 surface area. With this in mind, the disappearance of thiacloprid, a neonicotinoid insecticide, was studied applying various photochemical AOPs and different TiO2 photocatalysts. In photocatalytic ozonation experiments, synergic effect of three different TiO2 photocatalysts was quantified. Higher surface area resulted in a more pronounced synergic effect but an increasing amount of TiO2 did not influence the degree of the synergy. This supports the theory that the synergy is a consequence of adsorption of ozone on the TiO2 surface. No synergy was observed in photocatalytic degradation of thiacloprid in the presence of dissolved iron(III) species performed under varied experimental conditions. (en)
Title
  • Effect of dissolved ozone or ferric ions on photodegradation of thiacloprid in presence of different TiO2 catalysts
  • Effect of dissolved ozone or ferric ions on photodegradation of thiacloprid in presence of different TiO2 catalysts (en)
skos:prefLabel
  • Effect of dissolved ozone or ferric ions on photodegradation of thiacloprid in presence of different TiO2 catalysts
  • Effect of dissolved ozone or ferric ions on photodegradation of thiacloprid in presence of different TiO2 catalysts (en)
skos:notation
  • RIV/61388955:_____/10:00350961!RIV11-AV0-61388955
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika
  • 1-3
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 255957
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/10:00350961
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • neonicotionoid pesticides; photocatalysis; ozonation (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [D59187382363]
http://linked.open...i/riv/nazevZdroje
  • Journal of Hazardous Materials
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 177
http://linked.open...iv/tvurceVysledku
  • Jirkovský, Jaromír
  • Černigoj, U.
  • Štangar, U. L.
http://linked.open...ain/vavai/riv/wos
  • 000276154500050
http://linked.open...n/vavai/riv/zamer
issn
  • 0304-3894
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