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  • Carbon-templated mesoporous ZSM-5 zeolites were synthesized directly avoiding a drying process. Carbon nanoparticles were simply mixed into synthesis precursor of ZSM-5 and hydrothermally treated by microwave irradiation. The amount of mesopores formed inside the ZSM-5 single crystals was controllable by adjusting the amount of carbon used. For comparison, mesoporous ZSM-5 zeolites have also been synthesized under hydrothermal conditions. The influence of microwave irradiation on mesoporous ZSM-5 materials was thoroughly investigated by using nitrogen adsorption/desorption studies and 27Al MAS NMR. The nature of acid sites both in the micropores (internal) and on the surface of mesopores (external) was investigated by in situ FTIR spectroscopy using pyridine (Py) and 2,6-di-tert-butylpyridine (DTBPy) as a probe molecules.
  • Carbon-templated mesoporous ZSM-5 zeolites were synthesized directly avoiding a drying process. Carbon nanoparticles were simply mixed into synthesis precursor of ZSM-5 and hydrothermally treated by microwave irradiation. The amount of mesopores formed inside the ZSM-5 single crystals was controllable by adjusting the amount of carbon used. For comparison, mesoporous ZSM-5 zeolites have also been synthesized under hydrothermal conditions. The influence of microwave irradiation on mesoporous ZSM-5 materials was thoroughly investigated by using nitrogen adsorption/desorption studies and 27Al MAS NMR. The nature of acid sites both in the micropores (internal) and on the surface of mesopores (external) was investigated by in situ FTIR spectroscopy using pyridine (Py) and 2,6-di-tert-butylpyridine (DTBPy) as a probe molecules. (en)
Title
  • Direct synthesis of carbon-templating mesoporous ZSM-5 using microwave heating
  • Direct synthesis of carbon-templating mesoporous ZSM-5 using microwave heating (en)
skos:prefLabel
  • Direct synthesis of carbon-templating mesoporous ZSM-5 using microwave heating
  • Direct synthesis of carbon-templating mesoporous ZSM-5 using microwave heating (en)
skos:notation
  • RIV/61388955:_____/10:00349507!RIV11-AV0-61388955
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika
  • 2
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 254552
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/10:00349507
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • mesoporous ZSM-5; template; microwave irradiation; carbon (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [B64EF62563A2]
http://linked.open...i/riv/nazevZdroje
  • Journal of Catalysis
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 276
http://linked.open...iv/tvurceVysledku
  • Musilová, Zuzana
  • Čejka, Jiří
  • Bejblová, Martina
  • Park, S.-E.
  • Jiang, N.
  • Koo, J.-B.
  • Saravanamurugan, S.
http://linked.open...ain/vavai/riv/wos
  • 000285322800013
http://linked.open...n/vavai/riv/zamer
issn
  • 0021-9517
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