About: Ambi-Valence Taken Literally: Ruthenium vs Iron Oxidation in (1,1-Diphosphinoferrocene)ruthenium(II) Hydride and Chloride Complexes as Deduced from Spectroelectrochemistry of the Heterodimetallic “Mixed-Valent Intermediates

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About: Ambi-Valence Taken Literally: Ruthenium vs Iron Oxidation in (1,1-Diphosphinoferrocene)ruthenium(II) Hydride and Chloride Complexes as Deduced from Spectroelectrochemistry of the Heterodimetallic “Mixed-Valent Intermediates Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Combining two different redox-active organometallic moieties, we prepared the compounds [(Cym)RuCl(dpf)](PF6), with Cym = p-cymene = 1-isopropyl-4-methylbenzene, and the diphosphinoferrocenes (dpf) 1,1-bis(diphenylphosphino)ferrocene (dppf; complex 3), 1,1-bis(diisopropylphosphino)ferrocene (dippf; complex 4), and 1,1-bis(diethylphosphino)ferrocene (depf; complex 5) as well as the structurally characterized hydride complex [(C5Me5)RuH(dippf)] (2). In contrast to the case for 2, with an approximately staggered ferrocene conformation, the chloride complexes 35 exhibit a syn-periplanar ferrocene arrangement due to a ClH(C5H4) interaction in the solid and in solution. The related new compounds [(Cym)RuH(dppf)](PF6) (6) and trinuclear (μ-dpf)[(Cym)RuCl2)]2 (79) were also obtained and identified by 1H and 31P NMR spectroscopy. Combining two different redox-active organometallic moieties, we prepared the compounds [(Cym)RuCl(dpf)](PF6), with Cym = p-cymene = 1-isopropyl-4-methylbenzene, and the diphosphinoferrocenes (dpf) 1,1-bis(diphenylphosphino)ferrocene (dppf; complex 3), 1,1-bis(diisopropylphosphino)ferrocene (dippf; complex 4), and 1,1-bis(diethylphosphino)ferrocene (depf; complex 5) as well as the structurally characterized hydride complex [(C5Me5)RuH(dippf)] (2). In contrast to the case for 2, with an approximately staggered ferrocene conformation, the chloride complexes 35 exhibit a syn-periplanar ferrocene arrangement due to a ClH(C5H4) interaction in the solid and in solution. The related new compounds [(Cym)RuH(dppf)](PF6) (6) and trinuclear (μ-dpf)[(Cym)RuCl2)]2 (79) were also obtained and identified by 1H and 31P NMR spectroscopy. (en)
Title	Ambi-Valence Taken Literally: Ruthenium vs Iron Oxidation in (1,1-Diphosphinoferrocene)ruthenium(II) Hydride and Chloride Complexes as Deduced from Spectroelectrochemistry of the Heterodimetallic “Mixed-Valent Intermediates Ambi-Valence Taken Literally: Ruthenium vs Iron Oxidation in (1,1-Diphosphinoferrocene)ruthenium(II) Hydride and Chloride Complexes as Deduced from Spectroelectrochemistry of the Heterodimetallic “Mixed-Valent Intermediates (en)
skos:prefLabel	Ambi-Valence Taken Literally: Ruthenium vs Iron Oxidation in (1,1-Diphosphinoferrocene)ruthenium(II) Hydride and Chloride Complexes as Deduced from Spectroelectrochemistry of the Heterodimetallic “Mixed-Valent Intermediates Ambi-Valence Taken Literally: Ruthenium vs Iron Oxidation in (1,1-Diphosphinoferrocene)ruthenium(II) Hydride and Chloride Complexes as Deduced from Spectroelectrochemistry of the Heterodimetallic “Mixed-Valent Intermediates (en)
skos:notation	RIV/61388955:_____/10:00349260!RIV11-GA0-61388955
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/08/1157), P(GA203/09/0705), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika	21
http://linked.open...vai/riv/dodaniDat	2011
http://linked.open...aciTvurceVysledku	Fiedler, Jan
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	246096
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/10:00349260
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	(1,1-Diphosphinoferrocene)ruthenium(II); hydride complexes; chloriode complexes (en)
http://linked.open.../riv/klicoveSlovo	(1 1-Diphosphinoferrocene)ruthenium(II) chloriode complexes hydride complexes
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[5DF2BD03BB04]
http://linked.open...i/riv/nazevZdroje	Organometallics
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...vavai/riv/projekt	Transfer of charge in single and assembled molecules Tailoring the lock and key motifs in novel low-dimensional structures at electrified interface
http://linked.open...UplatneniVysledku	2010
http://linked.open...v/svazekPeriodika	29
http://linked.open...iv/tvurceVysledku	Fiedler, Jan Kaim, W. Sieger, M. Bubrin, D. Krafft, M. J. Sixt, T.
http://linked.open...ain/vavai/riv/wos	000283572100103
http://linked.open...n/vavai/riv/zamer	Struktura, reaktivita a dynamika molekulárních a biomolekulárních systémů: teorie, experiment, aplikace
issn	0276-7333
number of pages	6 (xsd:int)
is http://linked.open...avai/riv/vysledek of	Ambi-Valence Taken Literally: Ruthenium vs Iron Oxidation in (1,1-Diphosphinoferrocene)ruthenium(II) Hydride and Chloride Complexes as Deduced from Spectroelectrochemistry of the Heterodimetallic “Mixed-Valent Intermediates Ambi-Valence Taken Literally: Ruthenium vs Iron Oxidation in (1,1-Diphosphinoferrocene)ruthenium(II) Hydride and Chloride Complexes as Deduced from Spectroelectrochemistry of the Heterodimetallic “Mixed-Valent Intermediates Ambi-Valence Taken Literally: Ruthenium vs Iron Oxidation in (1,1-Diphosphinoferrocene)ruthenium(II) Hydride and Chloride Complexes as Deduced from Spectroelectrochemistry of the Heterodimetallic “Mixed-Valent Intermediates

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