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Description
  • Here we report the synthesis of a new redox-active ionic liquid (IL), (ferrocenylmethyl)dodecyldimethylammonium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate that can be used to form the polarizable waterIL interface at an elevated temperature (43 °C). Experimental approach is based on the cyclic voltammetry of the charge transfer processes occurring at the IL membrane supported on a thin microporous filter. Evidence is provided of the interfacial electron transfer between the ferrocenated cation of IL and an electron acceptor, IrCl62, in the adjacent aqueous phase.
  • Here we report the synthesis of a new redox-active ionic liquid (IL), (ferrocenylmethyl)dodecyldimethylammonium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate that can be used to form the polarizable waterIL interface at an elevated temperature (43 °C). Experimental approach is based on the cyclic voltammetry of the charge transfer processes occurring at the IL membrane supported on a thin microporous filter. Evidence is provided of the interfacial electron transfer between the ferrocenated cation of IL and an electron acceptor, IrCl62, in the adjacent aqueous phase. (en)
Title
  • Electron transfer across the polarized interface between water and a hydrophobic redox-active ionic liquid
  • Electron transfer across the polarized interface between water and a hydrophobic redox-active ionic liquid (en)
skos:prefLabel
  • Electron transfer across the polarized interface between water and a hydrophobic redox-active ionic liquid
  • Electron transfer across the polarized interface between water and a hydrophobic redox-active ionic liquid (en)
skos:notation
  • RIV/61388955:_____/10:00348376!RIV11-GA0-61388955
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GAP206/10/1231), P(ME08098), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika
  • 10
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 256757
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/10:00348376
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • redox-active ionic liquid; membrane; cyclic voltammetry (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [6A70FF173DBB]
http://linked.open...i/riv/nazevZdroje
  • Electrochemistry Communications
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 12
http://linked.open...iv/tvurceVysledku
  • Langmaier, Jan
  • Samec, Zdeněk
  • Trojánek, Antonín
http://linked.open...ain/vavai/riv/wos
  • 000284444500019
http://linked.open...n/vavai/riv/zamer
issn
  • 1388-2481
number of pages
is http://linked.open...avai/riv/vysledek of
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