About: Post-Synthesis Modification of SSZ-35 Zeolite to Enhance the Selectivity in p-Xylene Alkylation with Isopropyl Alcohol     Goto   Sponge   NotDistinct   Permalink

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  • Modification of textural and chemical properties of SSZ-35 was investigated in respect to the catalytic behavior of this zeolite in p-xylene alkylation with isopropyl alcohol. Acidic treatment of the external surface of SSZ-35 crystals resulted in a decrease in the void volume of the zeolite and in the concentration of acid sites mainly located on the external surface. This was evidenced from the FTIR spectra of adsorbed pyridine and 2,6-di-tert-butylpyridine. The modification caused a significant increase in the selectivity to 2,5-dimethylcumene while the p-xylene conversion decreased only very slightly.
  • Modification of textural and chemical properties of SSZ-35 was investigated in respect to the catalytic behavior of this zeolite in p-xylene alkylation with isopropyl alcohol. Acidic treatment of the external surface of SSZ-35 crystals resulted in a decrease in the void volume of the zeolite and in the concentration of acid sites mainly located on the external surface. This was evidenced from the FTIR spectra of adsorbed pyridine and 2,6-di-tert-butylpyridine. The modification caused a significant increase in the selectivity to 2,5-dimethylcumene while the p-xylene conversion decreased only very slightly. (en)
Title
  • Post-Synthesis Modification of SSZ-35 Zeolite to Enhance the Selectivity in p-Xylene Alkylation with Isopropyl Alcohol
  • Post-Synthesis Modification of SSZ-35 Zeolite to Enhance the Selectivity in p-Xylene Alkylation with Isopropyl Alcohol (en)
skos:prefLabel
  • Post-Synthesis Modification of SSZ-35 Zeolite to Enhance the Selectivity in p-Xylene Alkylation with Isopropyl Alcohol
  • Post-Synthesis Modification of SSZ-35 Zeolite to Enhance the Selectivity in p-Xylene Alkylation with Isopropyl Alcohol (en)
skos:notation
  • RIV/61388955:_____/10:00341713!RIV11-GA0-61388955
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(1QS400400560), P(GD203/08/H032), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika
  • 3-4
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 280375
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/10:00341713
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • SSZ-35; surface modification; p-xylene; 2,5-dimethylcumene (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [20D671D24789]
http://linked.open...i/riv/nazevZdroje
  • Topics in Catalysis
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 53
http://linked.open...iv/tvurceVysledku
  • Čejka, Jiří
  • Zones, S. I.
  • Pavlačková, Zuzana
http://linked.open...ain/vavai/riv/wos
  • 000275558000018
http://linked.open...n/vavai/riv/zamer
issn
  • 1022-5528
number of pages
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