About: Oxygen reduction by decamethylferrocene at liquid/liquid interfaces catalyzed by dodecylaniline

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Molecular oxygen (O-2) reduction by decamethylferrocene (DMFc) was investigated at a polarized water/1,2-dichloroethane (DCE) interface. Electrochemical results point to a mechanism similar to the EC type reaction at the conventional electrode/solution interface, in which an assisted proton transfer (APT) by DMFc across the water/DCE interface via the formation of DMFcH(+) corresponds to the electrochemical step and O-2 reduction to hydrogen peroxide (H2O2) represents the chemical step. The proton transfer step can also be driven using lipophilic bases such as 4-dodecylaniline. Finally, voltammetric data shows that lipophilic DMFc can also be extracted to the aqueous acidic phase to react homogeneously with oxygen. Molecular oxygen (O-2) reduction by decamethylferrocene (DMFc) was investigated at a polarized water/1,2-dichloroethane (DCE) interface. Electrochemical results point to a mechanism similar to the EC type reaction at the conventional electrode/solution interface, in which an assisted proton transfer (APT) by DMFc across the water/DCE interface via the formation of DMFcH(+) corresponds to the electrochemical step and O-2 reduction to hydrogen peroxide (H2O2) represents the chemical step. The proton transfer step can also be driven using lipophilic bases such as 4-dodecylaniline. Finally, voltammetric data shows that lipophilic DMFc can also be extracted to the aqueous acidic phase to react homogeneously with oxygen. (en)
Title	Oxygen reduction by decamethylferrocene at liquid/liquid interfaces catalyzed by dodecylaniline Oxygen reduction by decamethylferrocene at liquid/liquid interfaces catalyzed by dodecylaniline (en)
skos:prefLabel	Oxygen reduction by decamethylferrocene at liquid/liquid interfaces catalyzed by dodecylaniline Oxygen reduction by decamethylferrocene at liquid/liquid interfaces catalyzed by dodecylaniline (en)
skos:notation	RIV/61388955:_____/10:00341544!RIV11-GA0-61388955
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/07/1257), P(OC 177), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika	1-2
http://linked.open...vai/riv/dodaniDat	2011
http://linked.open...aciTvurceVysledku	Samec, Zdeněk
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	277892
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/10:00341544
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	oxygen reduction; proton reduction; voltammetry (en)
http://linked.open.../riv/klicoveSlovo	oxygen reduction voltammetry proton reduction
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[9F93EACFDFB5]
http://linked.open...i/riv/nazevZdroje	Journal of Electroanalytical Chemistry
http://linked.open...in/vavai/riv/obor	CG
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...vavai/riv/projekt	http://linked.opendata.cz/resource/domain/vavai/projekt/OC%20177 Molecular catalysis of the oxygen reduction at a polarised liquid-liquid interface
http://linked.open...UplatneniVysledku	2010
http://linked.open...v/svazekPeriodika	639
http://linked.open...iv/tvurceVysledku	Girault, H. H. Samec, Zdeněk Su, B. Li, F. Partovi-Nia, R. Hatay, I. Ersöz, M.
http://linked.open...ain/vavai/riv/wos	000275137400015
http://linked.open...n/vavai/riv/zamer	Struktura, reaktivita a dynamika molekulárních a biomolekulárních systémů: teorie, experiment, aplikace
issn	1572-6657
number of pages	7 (xsd:int)
is http://linked.open...avai/riv/vysledek of	Oxygen reduction by decamethylferrocene at liquid/liquid interfaces catalyzed by dodecylaniline

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