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  • Nanocrystalline Ru1-xNixO2 materials were synthesized by a solution method. Local structure around doped Ni atoms was characterized by extended X-ray absorption fine structure (EXAFS) functions obtained from X-ray absorption spectra acquired at Ni-K edge (8333eV). It was found that Ni ions are confined to the Ru site in the RuO2 rutile-type crystal structure, and Ni atoms tend to group by entering neighbouring sites along the body diagonal of rutile lattice. Such a neighbourhood of two Ni atoms may act as an active site for oxygen evolution by promoting simultaneous two electron transfer from the absorbed molecule of water. The refined Ni-O bond distances suggest that oxidation state of Ni ions is between +2 and +3.
  • Nanocrystalline Ru1-xNixO2 materials were synthesized by a solution method. Local structure around doped Ni atoms was characterized by extended X-ray absorption fine structure (EXAFS) functions obtained from X-ray absorption spectra acquired at Ni-K edge (8333eV). It was found that Ni ions are confined to the Ru site in the RuO2 rutile-type crystal structure, and Ni atoms tend to group by entering neighbouring sites along the body diagonal of rutile lattice. Such a neighbourhood of two Ni atoms may act as an active site for oxygen evolution by promoting simultaneous two electron transfer from the absorbed molecule of water. The refined Ni-O bond distances suggest that oxidation state of Ni ions is between +2 and +3. (en)
Title
  • Analysis of local structure of Ru1-xNixO2 electrocatalytic materials
  • Analysis of local structure of Ru1-xNixO2 electrocatalytic materials (en)
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  • Analysis of local structure of Ru1-xNixO2 electrocatalytic materials
  • Analysis of local structure of Ru1-xNixO2 electrocatalytic materials (en)
skos:notation
  • RIV/61388955:_____/09:00333662!RIV10-AV0-61388955
http://linked.open...avai/riv/aktivita
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  • Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika
  • 1
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  • 302893
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  • RIV/61388955:_____/09:00333662
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  • electrochemistry; electrocatalytic materials; nanocrystalline (en)
http://linked.open.../riv/klicoveSlovo
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  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [73AF1537FC96]
http://linked.open...i/riv/nazevZdroje
  • Journal of Physics, Conference Series
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http://linked.open...v/svazekPeriodika
  • 190
http://linked.open...iv/tvurceVysledku
  • Franc, Jiří
  • Krtil, Petr
  • Macounová, Kateřina
  • Petrykin, Valery
  • Okube, M.
http://linked.open...n/vavai/riv/zamer
issn
  • 1742-6596
number of pages
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