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  • Cyclic voltammetry is used to study the transfer of a series of cations and anions across a room-temperature ionic liquid membrane composed of tridodecylmethylammonium cation and tetrakis[3,5-bis(trifluoromethyl) phenyl]borate anion. It is shown that the addition of water-soluble crown ether (e.g. 18-crown-6) to the aqueous phase makes it possible to distinguish the voltammetric responses of alkali and alkaline earth metal cations. The determination of low concentrations of K+ (0.05-0.3 mM) in the presence of an excess of Mg2+ (1 mM) in water is demonstrated as a model application of an amperometric ion-selective electrode for K+.
  • Cyclic voltammetry is used to study the transfer of a series of cations and anions across a room-temperature ionic liquid membrane composed of tridodecylmethylammonium cation and tetrakis[3,5-bis(trifluoromethyl) phenyl]borate anion. It is shown that the addition of water-soluble crown ether (e.g. 18-crown-6) to the aqueous phase makes it possible to distinguish the voltammetric responses of alkali and alkaline earth metal cations. The determination of low concentrations of K+ (0.05-0.3 mM) in the presence of an excess of Mg2+ (1 mM) in water is demonstrated as a model application of an amperometric ion-selective electrode for K+. (en)
Title
  • Amperometric Ion-Selective Electrode for Alkali Metal Cations Based on a Room-Temperature Ionic Liquid Membrane
  • Amperometric Ion-Selective Electrode for Alkali Metal Cations Based on a Room-Temperature Ionic Liquid Membrane (en)
skos:prefLabel
  • Amperometric Ion-Selective Electrode for Alkali Metal Cations Based on a Room-Temperature Ionic Liquid Membrane
  • Amperometric Ion-Selective Electrode for Alkali Metal Cations Based on a Room-Temperature Ionic Liquid Membrane (en)
skos:notation
  • RIV/61388955:_____/09:00329201!RIV10-MSM-61388955
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(IAA400400704), P(ME08098), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika
  • 17-18
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 302655
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/09:00329201
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • room-temperature ionic liquid; alkali metals; Crown ether; cyclic voltammetry; amperometric ion-selective elkectrode (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [E32C37A8A1B2]
http://linked.open...i/riv/nazevZdroje
  • Electroanalysis
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 21
http://linked.open...iv/tvurceVysledku
  • Langmaier, Jan
  • Samec, Zdeněk
  • Trojánek, Antonín
http://linked.open...ain/vavai/riv/wos
  • 000270399100013
http://linked.open...n/vavai/riv/zamer
issn
  • 1040-0397
number of pages
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