About: Heterohexanuclear (Cu3Fe3) Complexes of Substituted Hexaazatrinaphthylene (HATN) Ligands: Twofold BF4- Association in the Solid and Stepwise Oxidation (3 e) or Reduction (2 e) to Spectroelectrochemically Characterized Species

Facets (new session)
Description
Metadata
Settings
- owl:sameAs
- Inference Rule:

About: Heterohexanuclear (Cu3Fe3) Complexes of Substituted Hexaazatrinaphthylene (HATN) Ligands: Twofold BF4- Association in the Solid and Stepwise Oxidation (3 e) or Reduction (2 e) to Spectroelectrochemically Characterized Species Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	New tris(ferrocenylcopper) compounds {(.mu.3-dqp)[Cu(dppf)]3}(BF4)3, dppf = 1,1’-bis(diphenylphosphinoferrocene), dqp = hexamethyl-, hexachloro- and un-substituted diquinoxalino[2,3-a:2’,3’-c]phenazine = hexaazatrinaphthylene (HATN), undergo at least two differently separated reversible one-electron reductions and three very closely spaced one-electron oxidations. While the latter are attributed to the stepwise ferrocene->ferrocenium conversions, the first electron addition occurs in the ligand bridge to yield EPR detectable radical complexes. All reversible steps were investigated by OTTLE spectroelectrochemistry in the UV, Vis and NIR regions, revealing very low energy transitions for the reduced forms in agreement with the frontier MO arrangement. New tris(ferrocenylcopper) compounds {(.mu.3-dqp)[Cu(dppf)]3}(BF4)3, dppf = 1,1’-bis(diphenylphosphinoferrocene), dqp = hexamethyl-, hexachloro- and un-substituted diquinoxalino[2,3-a:2’,3’-c]phenazine = hexaazatrinaphthylene (HATN), undergo at least two differently separated reversible one-electron reductions and three very closely spaced one-electron oxidations. While the latter are attributed to the stepwise ferrocene->ferrocenium conversions, the first electron addition occurs in the ligand bridge to yield EPR detectable radical complexes. All reversible steps were investigated by OTTLE spectroelectrochemistry in the UV, Vis and NIR regions, revealing very low energy transitions for the reduced forms in agreement with the frontier MO arrangement. (en)
Title	Heterohexanuclear (Cu3Fe3) Complexes of Substituted Hexaazatrinaphthylene (HATN) Ligands: Twofold BF4- Association in the Solid and Stepwise Oxidation (3 e) or Reduction (2 e) to Spectroelectrochemically Characterized Species Heterohexanuclear (Cu3Fe3) Complexes of Substituted Hexaazatrinaphthylene (HATN) Ligands: Twofold BF4- Association in the Solid and Stepwise Oxidation (3 e) or Reduction (2 e) to Spectroelectrochemically Characterized Species (en)
skos:prefLabel	Heterohexanuclear (Cu3Fe3) Complexes of Substituted Hexaazatrinaphthylene (HATN) Ligands: Twofold BF4- Association in the Solid and Stepwise Oxidation (3 e) or Reduction (2 e) to Spectroelectrochemically Characterized Species Heterohexanuclear (Cu3Fe3) Complexes of Substituted Hexaazatrinaphthylene (HATN) Ligands: Twofold BF4- Association in the Solid and Stepwise Oxidation (3 e) or Reduction (2 e) to Spectroelectrochemically Characterized Species (en)
skos:notation	RIV/61388955:_____/09:00327325!RIV10-MSM-61388955
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(OC 139), P(OC 140), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika	28
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Fiedler, Jan
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	317052
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/09:00327325
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	copper; EPR spectroscopy; ferrocene compounds; heterocycles; spectroelectrochemistry (en)
http://linked.open.../riv/klicoveSlovo	copper EPR spectroscopy heterocycles spectroelectrochemistry ferrocene compounds
http://linked.open...odStatuVydavatele	DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV	[233989858D48]
http://linked.open...i/riv/nazevZdroje	Chemistry - A European Journal
http://linked.open...in/vavai/riv/obor	CG
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	9 (xsd:int)
http://linked.open...vavai/riv/projekt	http://linked.opendata.cz/resource/domain/vavai/projekt/OC%20140 http://linked.opendata.cz/resource/domain/vavai/projekt/OC%20139
http://linked.open...UplatneniVysledku	2009
http://linked.open...v/svazekPeriodika	15
http://linked.open...iv/tvurceVysledku	Fiedler, Jan Kaim, W. Lahiri, G. K. Mobin, S. M. Sarkar, B. Roy, S. Lissner, F. Sarper, O. Duboc, C.
http://linked.open...ain/vavai/riv/wos	000268286200021
http://linked.open...n/vavai/riv/zamer	Struktura, reaktivita a dynamika molekulárních a biomolekulárních systémů: teorie, experiment, aplikace
issn	0947-6539
number of pages	8 (xsd:int)
is http://linked.open...avai/riv/vysledek of	Heterohexanuclear (Cu3Fe3) Complexes of Substituted Hexaazatrinaphthylene (HATN) Ligands: Twofold BF4- Association in the Solid and Stepwise Oxidation (3 e) or Reduction (2 e) to Spectroelectrochemically Characterized Species Heterohexanuclear (Cu3Fe3) Complexes of Substituted Hexaazatrinaphthylene (HATN) Ligands: Twofold BF4- Association in the Solid and Stepwise Oxidation (3 e) or Reduction (2 e) to Spectroelectrochemically Characterized Species Heterohexanuclear (Cu3Fe3) Complexes of Substituted Hexaazatrinaphthylene (HATN) Ligands: Twofold BF4- Association in the Solid and Stepwise Oxidation (3 e) or Reduction (2 e) to Spectroelectrochemically Characterized Species Heterohexanuclear (Cu3Fe3) Complexes of Substituted Hexaazatrinaphthylene (HATN) Ligands: Twofold BF4- Association in the Solid and Stepwise Oxidation (3 e) or Reduction (2 e) to Spectroelectrochemically Characterized Species

Faceted Search & Find service v1.16.118 as of Jun 21 2024

Alternative Linked Data Documents: ODE Content Formats:

RDF

ODATA

Microdata

About

OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 58 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software