About: A series of metal complexes with the non-innocent N,N’-Bis(pentafluorophenyl)-o-phenylenediamido ligand: twisted geometry for tuning the electronic structure     Goto   Sponge   NotDistinct   Permalink

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  • A series of homoleptic complexes with non-innocent ligands derived from N,N’ -bis(pentafluorophenyl)-o-phenylenediamine (H2Fpda) are reported. [NiII(Fsbqdi)2] (1), [PdII(Fsbqdi)2] (2), [CoII(Fsbqdi)2] (3), and [CuII(Fsbqdi)2] (4) were synthesized, where (Fsbqdi)1- represents a radical anion formed by one-electron oxidation of the doubly deprotonated H2Fpda. Complex 4 is the first CuII complex where both o-phenylenediamine derived ligands are monoanionic radicals. The electronic structures of the neutral compounds 1-4 and of some of their cationic and/or anionic neighboring redox states were probed using EPR and UV-VIS-NIR spectroelectrochemistry. The twisted geometry of the complexes results in considerable changes in their electronic structures compared to the well known square-planar complexes.
  • A series of homoleptic complexes with non-innocent ligands derived from N,N’ -bis(pentafluorophenyl)-o-phenylenediamine (H2Fpda) are reported. [NiII(Fsbqdi)2] (1), [PdII(Fsbqdi)2] (2), [CoII(Fsbqdi)2] (3), and [CuII(Fsbqdi)2] (4) were synthesized, where (Fsbqdi)1- represents a radical anion formed by one-electron oxidation of the doubly deprotonated H2Fpda. Complex 4 is the first CuII complex where both o-phenylenediamine derived ligands are monoanionic radicals. The electronic structures of the neutral compounds 1-4 and of some of their cationic and/or anionic neighboring redox states were probed using EPR and UV-VIS-NIR spectroelectrochemistry. The twisted geometry of the complexes results in considerable changes in their electronic structures compared to the well known square-planar complexes. (en)
  • Řada homoleptických komplexů s non-innocent ligandy odvozených od N,N' -bis(pentafluorofenyl)-o-fenylenediamine (H2Fpda) je popsána. [NiII(Fsbqdi)2] (1), [PdII(Fsbqdi)2] (2), [CoII(Fsbqdi)2] (3), a [CuII(Fsbqdi)2] (4) byl syntetizovány, kde (Fsbqdi)1- reprezentuje radikálový anion vytvořený jednoelektronovou oxidací dvojnásobně deprotonovaného H2Fpda. Komplex 4 je první CuII komplex, kde oba o-fenylenediaminové ligandy jsou monoanionickými radikály. Elektronové struktury neutrálních sloučenin 1-4 a některých jejich kationických a anionických redox stavů byly prověřeny s použitím EPR a UV-VIS-NIR spektroelektrochemie. Zkroucená geometrie komplexů způsobuje značné změny v jejich elektronových strukturách ve srovnání se známými čtvercově-planárními komplexy. (cs)
Title
  • A series of metal complexes with the non-innocent N,N’-Bis(pentafluorophenyl)-o-phenylenediamido ligand: twisted geometry for tuning the electronic structure
  • Řada kovových komplexů s non-innocent ligandem N,N'-Bis(pentafluorofenyl)-o-fenylendiamido: nastavení elektronové struktury vlivem zkroucené geometrie (cs)
  • A series of metal complexes with the non-innocent N,N’-Bis(pentafluorophenyl)-o-phenylenediamido ligand: twisted geometry for tuning the electronic structure (en)
skos:prefLabel
  • A series of metal complexes with the non-innocent N,N’-Bis(pentafluorophenyl)-o-phenylenediamido ligand: twisted geometry for tuning the electronic structure
  • Řada kovových komplexů s non-innocent ligandem N,N'-Bis(pentafluorofenyl)-o-fenylendiamido: nastavení elektronové struktury vlivem zkroucené geometrie (cs)
  • A series of metal complexes with the non-innocent N,N’-Bis(pentafluorophenyl)-o-phenylenediamido ligand: twisted geometry for tuning the electronic structure (en)
skos:notation
  • RIV/61388955:_____/08:00315010!RIV09-AV0-61388955
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(OC 139), P(OC 140), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika
  • 10
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 354491
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/08:00315010
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • metal complexes; non-innocent N,N’-Bis(pentafluorophenyl)-o-phenylenediamido ligand; electronic structure (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [DB28372E9F32]
http://linked.open...i/riv/nazevZdroje
  • Dalton Transactions
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • -
http://linked.open...iv/tvurceVysledku
  • Fiedler, Jan
  • Kaim, W.
  • Sarkar, B.
  • van Slageren, J.
  • Khusniyarov, M. M.
  • Burghaus, O.
  • Duboc, C.
  • Harms, K.
  • Sundermayer, J.
http://linked.open...n/vavai/riv/zamer
issn
  • 1477-9226
number of pages
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