About: HNC and HCN in an extended negative glow discharge: Implication to the branching ratio of the dissociative recombination of HCNH+

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Submillimeter-wave transitions of HNC and HCN are observed in an extended negative glow discharge in a gas Mixture of CH4 and N-2. It is well established that the extended negative glow discharge is a good source for production of positive ions for microwave observations which need lower gas pressures to avoid the line broadening. The branching ratio of the dissociative recombination to lead to HCN and HNC is derived from the abundance ratio by examining the temperature dependence of the signal intensities of the lines of HCN and HNC as well as HCNH+. The branching ratio thus obtained is 3 with an estimated uncertainty of 20% for the normal species and 1.5 for the deuterated species. The larger ratio for the normal species might be Caused by isomerization of HNC to HCN. Submillimeter-wave transitions of HNC and HCN are observed in an extended negative glow discharge in a gas Mixture of CH4 and N-2. It is well established that the extended negative glow discharge is a good source for production of positive ions for microwave observations which need lower gas pressures to avoid the line broadening. The branching ratio of the dissociative recombination to lead to HCN and HNC is derived from the abundance ratio by examining the temperature dependence of the signal intensities of the lines of HCN and HNC as well as HCNH+. The branching ratio thus obtained is 3 with an estimated uncertainty of 20% for the normal species and 1.5 for the deuterated species. The larger ratio for the normal species might be Caused by isomerization of HNC to HCN. (en) Submilimetrové přechody HNC a HCN byly pozorovány v prodlouženém negativním doutnavém výboji ve směsi CH4 a N2. Dělící poměr disociativní rekombinace byl odvozen z koncentračních poměrů pomocí teplotních závislostí iántenzit signálů linií HCN, HNC a rovněž HCNH+. (cs)
Title	HNC and HCN in an extended negative glow discharge: Implication to the branching ratio of the dissociative recombination of HCNH+ HNC and HCN in an extended negative glow discharge: Implication to the branching ratio of the dissociative recombination of HCNH+ (en) HNC a HCN v prodlouženém negativním doutnavém výboji: implikace k dělícímu poměru disociativní rekombinace HCNH+ (cs)
skos:prefLabel	HNC and HCN in an extended negative glow discharge: Implication to the branching ratio of the dissociative recombination of HCNH+ HNC and HCN in an extended negative glow discharge: Implication to the branching ratio of the dissociative recombination of HCNH+ (en) HNC a HCN v prodlouženém negativním doutnavém výboji: implikace k dělícímu poměru disociativní rekombinace HCNH+ (cs)
skos:notation	RIV/61388955:_____/08:00314679!RIV09-AV0-61388955
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika	1-2
http://linked.open...vai/riv/dodaniDat	2009
http://linked.open...aciTvurceVysledku	Zelinger, Zdeněk
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	370343
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/08:00314679
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	submillimeter-wave; molecular ions; dissociative recombination (en)
http://linked.open.../riv/klicoveSlovo	dissociative recombination molecular ions submillimeter-wave
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[793115E27113]
http://linked.open...i/riv/nazevZdroje	Journal of Molecular Spectroscopy
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...UplatneniVysledku	2008
http://linked.open...v/svazekPeriodika	251
http://linked.open...iv/tvurceVysledku	Zelinger, Zdeněk Amano, T. Hirao, T. Takano, J. Toyoda, R.
http://linked.open...ain/vavai/riv/wos	000259167900031
http://linked.open...n/vavai/riv/zamer	Struktura, reaktivita a dynamika molekulárních a biomolekulárních systémů: teorie, experiment, aplikace
issn	0022-2852
number of pages	4 (xsd:int)
is http://linked.open...avai/riv/vysledek of	HNC and HCN in an extended negative glow discharge: Implication to the branching ratio of the dissociative recombination of HCNH+ HNC and HCN in an extended negative glow discharge: Implication to the branching ratio of the dissociative recombination of HCNH+ HNC and HCN in an extended negative glow discharge: Implication to the branching ratio of the dissociative recombination of HCNH+ HNC and HCN in an extended negative glow discharge: Implication to the branching ratio of the dissociative recombination of HCNH+

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