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| rdf:type
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| Description
| - 3,6-Bis(2-thienyl)-1,2,4,5-tetrazine (bttz) reacts with trans-Pt(dmso)2(mes)2, mes = mesityl = 2,4,6-trimethylphenyl, under twofold cyclometallation to yield structurally characterized (.mu.-bttz-2H+)[Pt(dmso)(mes)]2 with uncoordinated thiophene sulfur atoms and bttz deprotonated in the 3,3´ positions. The structural features include cis-positioned carbanionic ligands, twisted mesityl substituents, S-coordinated dmso ligands with the S=O bonds lying in the molecular plane, shortened inter-ring bonds, and rather short Pt-C bonds.Reversible reduction to {(.mu.-bttz-2H+)[Pt(dmso)(mes)]2}.- causes a high-energy shift of the charge transfer bands and the appearance of an unresolved EPR signal at g = 1.9905.
- 3,6-Bis(2-thienyl)-1,2,4,5-tetrazine (bttz) reacts with trans-Pt(dmso)2(mes)2, mes = mesityl = 2,4,6-trimethylphenyl, under twofold cyclometallation to yield structurally characterized (.mu.-bttz-2H+)[Pt(dmso)(mes)]2 with uncoordinated thiophene sulfur atoms and bttz deprotonated in the 3,3´ positions. The structural features include cis-positioned carbanionic ligands, twisted mesityl substituents, S-coordinated dmso ligands with the S=O bonds lying in the molecular plane, shortened inter-ring bonds, and rather short Pt-C bonds.Reversible reduction to {(.mu.-bttz-2H+)[Pt(dmso)(mes)]2}.- causes a high-energy shift of the charge transfer bands and the appearance of an unresolved EPR signal at g = 1.9905. (en)
- 3,6-Bis(2-thienyl)-1,2,4,5-tetrazin (bttz) reaguje s trans-Pt(dmso)2(mes)2, mes = mesityl = 2,4,6-trimethylfenyl, za dvojité cyklometalace a poskytuje strukturně charakterizovaný (.mu.-bttz-2H+)[Pt(dmso)(mes)]2 s nekoordinovanými sírovými atomy thiofenu a s bttz deprotonovaným v 3,3´ pozicích. Strukturní rysy zahrnují cis-pozici karbanionových ligandů, stočené mesityl substituenty, S-koordinované dmso ligandy s S=O vazbami ležícími rovině molekuly, zkrácené vnitřní vazby kruhu a dosti krátké vazby Pt-C. Reversibilní redukce na {(.mu.-bttz-2H+)[Pt(dmso)(mes )]2}.- způsobuje posun pásů přenosu náboje k vyšším energiím a vznik nerozlišeného EPR signálu při g = 1.9905. (cs)
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| Title
| - Double cyclometallation of bridging 3,6-bis(2-thienyl)-1,2,4,5-tetrazine in a dinuclear mesityl(dimethylsulfoxide)platinum(II) complex: Structure and properties
- Dvojitá cyklometalace můstkového 3,6-bis(2-thienyl)-1,2,4,5-tetrazinu v dvojjaderném mesityl(dimethylsulfoxid)platinovém(II) komplexu: Struktura a vlastnosti (cs)
- Double cyclometallation of bridging 3,6-bis(2-thienyl)-1,2,4,5-tetrazine in a dinuclear mesityl(dimethylsulfoxide)platinum(II) complex: Structure and properties (en)
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| skos:prefLabel
| - Double cyclometallation of bridging 3,6-bis(2-thienyl)-1,2,4,5-tetrazine in a dinuclear mesityl(dimethylsulfoxide)platinum(II) complex: Structure and properties
- Dvojitá cyklometalace můstkového 3,6-bis(2-thienyl)-1,2,4,5-tetrazinu v dvojjaderném mesityl(dimethylsulfoxid)platinovém(II) komplexu: Struktura a vlastnosti (cs)
- Double cyclometallation of bridging 3,6-bis(2-thienyl)-1,2,4,5-tetrazine in a dinuclear mesityl(dimethylsulfoxide)platinum(II) complex: Structure and properties (en)
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| skos:notation
| - RIV/61388955:_____/08:00309639!RIV09-AV0-61388955
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| http://linked.open...avai/riv/aktivita
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| http://linked.open...avai/riv/aktivity
| - P(1P05OC068), P(OC 139), Z(AV0Z40400503)
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| http://linked.open...iv/cisloPeriodika
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| http://linked.open...vai/riv/dodaniDat
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| http://linked.open...aciTvurceVysledku
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| http://linked.open.../riv/druhVysledku
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| http://linked.open...iv/duvernostUdaju
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| http://linked.open...titaPredkladatele
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| http://linked.open...dnocenehoVysledku
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| http://linked.open...ai/riv/idVysledku
| - RIV/61388955:_____/08:00309639
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| http://linked.open...riv/jazykVysledku
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| http://linked.open.../riv/klicovaSlova
| - crystal structure; cyclometallation; EPR spectroscopy; heterocyclic ligand (en)
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| http://linked.open.../riv/klicoveSlovo
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| http://linked.open...odStatuVydavatele
| - CH - Švýcarská konfederace
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| http://linked.open...ontrolniKodProRIV
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| http://linked.open...i/riv/nazevZdroje
| - Journal of Organometallic Chemistry
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| http://linked.open...in/vavai/riv/obor
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| http://linked.open...ichTvurcuVysledku
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| http://linked.open...cetTvurcuVysledku
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| http://linked.open...vavai/riv/projekt
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| http://linked.open...UplatneniVysledku
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| http://linked.open...v/svazekPeriodika
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| http://linked.open...iv/tvurceVysledku
| - Fiedler, Jan
- Hartenbach, I.
- Kaim, W.
- Sarkar, B.
- Schleid, T.
- Schurr, T.
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| http://linked.open...ain/vavai/riv/wos
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| http://linked.open...n/vavai/riv/zamer
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| issn
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| number of pages
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| is http://linked.open...avai/riv/vysledek
of | - Double cyclometallation of bridging 3,6-bis(2-thienyl)-1,2,4,5-tetrazine in a dinuclear mesityl(dimethylsulfoxide)platinum(II) complex: Structure and properties
- Double cyclometallation of bridging 3,6-bis(2-thienyl)-1,2,4,5-tetrazine in a dinuclear mesityl(dimethylsulfoxide)platinum(II) complex: Structure and properties
- Double cyclometallation of bridging 3,6-bis(2-thienyl)-1,2,4,5-tetrazine in a dinuclear mesityl(dimethylsulfoxide)platinum(II) complex: Structure and properties
- Double cyclometallation of bridging 3,6-bis(2-thienyl)-1,2,4,5-tetrazine in a dinuclear mesityl(dimethylsulfoxide)platinum(II) complex: Structure and properties
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