About: Ag Active Sites, Surface Intermediates and Hydrogen Function at decane-SCR-Nox over Ag/Alumina     Goto   Sponge   NotDistinct   Permalink

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  • The state of silver and surface intermediates were simultaneously analyzed at real decane-SCR-NOx reaction conditions as well as at the individual reaction steps and those reactions under addition of hydrogen or H2O2 with an attempt to elucidate the active Ag site and hydrogen function. The enhanced activity by the addition of hydrogen to the NOx-SCR mix cannot be attributed exclusively to the formation of Ag clusters. The active sites are suggested to be Ag+ ions and hydrogen itself takes part in the SCR-NOx reaction. It dissociates, forms Ag-hydride, and radical-type reactions are supposed to enhance SCR-NOx.
  • The state of silver and surface intermediates were simultaneously analyzed at real decane-SCR-NOx reaction conditions as well as at the individual reaction steps and those reactions under addition of hydrogen or H2O2 with an attempt to elucidate the active Ag site and hydrogen function. The enhanced activity by the addition of hydrogen to the NOx-SCR mix cannot be attributed exclusively to the formation of Ag clusters. The active sites are suggested to be Ag+ ions and hydrogen itself takes part in the SCR-NOx reaction. It dissociates, forms Ag-hydride, and radical-type reactions are supposed to enhance SCR-NOx. (en)
Title
  • Ag Active Sites, Surface Intermediates and Hydrogen Function at decane-SCR-Nox over Ag/Alumina
  • Ag Active Sites, Surface Intermediates and Hydrogen Function at decane-SCR-Nox over Ag/Alumina (en)
skos:prefLabel
  • Ag Active Sites, Surface Intermediates and Hydrogen Function at decane-SCR-Nox over Ag/Alumina
  • Ag Active Sites, Surface Intermediates and Hydrogen Function at decane-SCR-Nox over Ag/Alumina (en)
skos:notation
  • RIV/61388955:_____/07:00322715!RIV10-AV0-61388955
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(1ET400400413), P(GD203/03/H140), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika
  • -
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 408733
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/07:00322715
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • SCR-NOx; Ag active sites; surface intermediates (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [EFBE57ACBCE0]
http://linked.open...i/riv/nazevZdroje
  • Studies in Surface Science and Catalysis
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 172
http://linked.open...iv/tvurceVysledku
  • Dědeček, Jiří
  • Nováková, Jana
  • Sazama, Petr
  • Sobalík, Zdeněk
  • Wichterlová, Blanka
http://linked.open...n/vavai/riv/zamer
issn
  • 0167-2991
number of pages
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