About: The change of the state of an endohedral fullerene by encapsulation into SWCNT: a Raman spectroelectrochemical study of Dy3N@C80 peapods

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About: The change of the state of an endohedral fullerene by encapsulation into SWCNT: a Raman spectroelectrochemical study of Dy3N@C80 peapods Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	A Raman and in situ Raman spectroelectrochemical study of Dy3N@C80@SWCNT peapods has been carried out for the first time. The formation of peapods via the encapsulation of gaseous Dy3N@C80 has been confirmed by HR-TEM microscopy and by the successful transformation of Dy3N@C80@SWCNT into double-wall carbon nanotubes. The Raman spectra of the endohedral clusterfullerene are dramatically changed in the interior of the single walled carbon nanotube. The electrochemical charging of the peapod indicates a slight reversible attenuation of the Raman intensities of fullerene features during anodic doping. The results support the assignment of Raman bands to the Dy3N@C80 inside SWCNT. A Raman and in situ Raman spectroelectrochemical study of Dy3N@C80@SWCNT peapods has been carried out for the first time. The formation of peapods via the encapsulation of gaseous Dy3N@C80 has been confirmed by HR-TEM microscopy and by the successful transformation of Dy3N@C80@SWCNT into double-wall carbon nanotubes. The Raman spectra of the endohedral clusterfullerene are dramatically changed in the interior of the single walled carbon nanotube. The electrochemical charging of the peapod indicates a slight reversible attenuation of the Raman intensities of fullerene features during anodic doping. The results support the assignment of Raman bands to the Dy3N@C80 inside SWCNT. (en) V této práci je presentována první in situ Raman spektroelektrochemická studie Dy3N@C80@SWCNT peapodů. Peapody byly připraveny sublimací Dy3N@C80 do SWCNT. Vytvoření peapodů bylo potvrzeno pomocí HRTEM a úspěšnou transformací Dy3N@C80@SWCNT na dvojstěnné uhlíkové nanotuby. Ramanská spektra endohedrálního fullerenu se uvnitř nanotuby významně změnila. Během elektrochemického anodického dopování peapodů došlo k reverzibilnímu vyhasínání Ramanského signálu. Výsledky potvrzují naše přiřazení Ramanských pásů Dy3N@C80 uvnitř SWCNT. (cs)
Title	The change of the state of an endohedral fullerene by encapsulation into SWCNT: a Raman spectroelectrochemical study of Dy3N@C80 peapods Změny v endohedrálním fullerenu vyvolané sublimací do SWCNT: Ramano- spektroelektrochemická studie Dy3N@C80 peapodů (cs) The change of the state of an endohedral fullerene by encapsulation into SWCNT: a Raman spectroelectrochemical study of Dy3N@C80 peapods (en)
skos:prefLabel	The change of the state of an endohedral fullerene by encapsulation into SWCNT: a Raman spectroelectrochemical study of Dy3N@C80 peapods Změny v endohedrálním fullerenu vyvolané sublimací do SWCNT: Ramano- spektroelektrochemická studie Dy3N@C80 peapodů (cs) The change of the state of an endohedral fullerene by encapsulation into SWCNT: a Raman spectroelectrochemical study of Dy3N@C80 peapods (en)
skos:notation	RIV/61388955:_____/07:00090807!RIV08-MSM-61388955
http://linked.open.../vavai/riv/strany	8811;8817
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(KJB400400601), P(LC510), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika	-
http://linked.open...vai/riv/dodaniDat	2008
http://linked.open...aciTvurceVysledku	Zukalová, Markéta Kavan, Ladislav Kalbáč, Martin
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	413203
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/07:00090807
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	dysprosium; electrochemistry; fullerenes; nanotubes (en)
http://linked.open.../riv/klicoveSlovo	nanotubes dysprosium electrochemistry fullerenes
http://linked.open...odStatuVydavatele	DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV	[996D99620AA2]
http://linked.open...i/riv/nazevZdroje	Chemistry - A European Journal
http://linked.open...in/vavai/riv/obor	CG
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...vavai/riv/projekt	Center of nanotechnology and materials for nanoelectronics Electrochemical and spectroelectrochemical study of carbon nanostructures
http://linked.open...UplatneniVysledku	2007
http://linked.open...v/svazekPeriodika	13
http://linked.open...iv/tvurceVysledku	Dunsch, L. Kalbáč, Martin Kavan, Ladislav Zukalová, Markéta Roth, S. Yang, S. Čech, J.
http://linked.open...n/vavai/riv/zamer	Struktura, reaktivita a dynamika molekulárních a biomolekulárních systémů: teorie, experiment, aplikace
issn	0947-6539
number of pages	7 (xsd:int)
is http://linked.open...avai/riv/vysledek of	The change of the state of an endohedral fullerene by encapsulation into SWCNT: a Raman spectroelectrochemical study of Dy3N@C80 peapods The change of the state of an endohedral fullerene by encapsulation into SWCNT: a Raman spectroelectrochemical study of Dy3N@C80 peapods The change of the state of an endohedral fullerene by encapsulation into SWCNT: a Raman spectroelectrochemical study of Dy3N@C80 peapods

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