About: In situ Raman spectroelectrochemical study of 13C labeled fullerene peapods and double walled carbon nanotubes     Goto   Sponge   NotDistinct   Permalink

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  • Fullerenové peapody C60 a dvojstěnné uhlíkové nanotuby (DWCNT) obsahující C60 a vnitřní tuby vysoce obohacené o 13C byly studovány pomocí Ramanské spektroskopie a in situ Ramanské spektroelektrochemie za účelem sledování vlivu obohacení uhlíkem 13C na spektra těchto nanostruktur. Bylo zjištěno, že Ramanský signál 13C60 uvnitř uhlíkové nanotuby je odlišný od signálu NatC60. Ramanský pás Ag(2) modu 13C60, který je uvnitř tuby, je posunut k vyšším frekvencím ve srovnání s modem NatC60 v tubách se stejným stupněm naplnění. Chemické dopování 13C60 peapodů parou draslíku vedlo k posunu Ag(2) modu podobně jako tomu bylo v případě NatC60 peapodů. Peapody 13C60 byly úspěšně transformovány na dvojstěnné uhlíkové nanotuby, což potvrzuje vysoký stupeň naplnění původních peapodů. U těchto DWCNT byly posunuty k nižším frekvencím pouze TG a D mody vnitřních tub což potvrzuje, že pouze vnitřní tuby jsou obohaceny uhlíkem 13C. (cs)
  • The C60 fullerene peapods and double walled carbon nanotubes (DWCNTs) containing highly 13C enriched C60 and inner tubes, respectively have been studied using Raman spectroscopy and in-situ Raman spectroelectrochemistry in order to follow the influence of 13C enrichment on vibrational pattern of these carbon nanostructures. The Raman response of 13C60 after encapsulation in fullerene peapods differs from that of isotope-natural species, NatC60. The Raman Ag(2) mode of encapsulated 13C60 is upshifted in frequency compared to that in NatC60 peapods with the same filling factor. The chemical doping of 13C60 peapods with K-vapor leads to the downshift of Ag(2) mode similarly as in case of NatC60 peapods. The 13C60 peapods were successfully transformed into DWCNTs, which confirms high filling of SWCNT with 13C60. The DWCNTs exhibited distinctly downshifted TG and D Raman modes for inner tubes, which confirms that only inner tubes were enriched by 13C.
  • The C60 fullerene peapods and double walled carbon nanotubes (DWCNTs) containing highly 13C enriched C60 and inner tubes, respectively have been studied using Raman spectroscopy and in-situ Raman spectroelectrochemistry in order to follow the influence of 13C enrichment on vibrational pattern of these carbon nanostructures. The Raman response of 13C60 after encapsulation in fullerene peapods differs from that of isotope-natural species, NatC60. The Raman Ag(2) mode of encapsulated 13C60 is upshifted in frequency compared to that in NatC60 peapods with the same filling factor. The chemical doping of 13C60 peapods with K-vapor leads to the downshift of Ag(2) mode similarly as in case of NatC60 peapods. The 13C60 peapods were successfully transformed into DWCNTs, which confirms high filling of SWCNT with 13C60. The DWCNTs exhibited distinctly downshifted TG and D Raman modes for inner tubes, which confirms that only inner tubes were enriched by 13C. (en)
Title
  • In situ Raman spectroelectrochemical study of 13C labeled fullerene peapods and double walled carbon nanotubes
  • In situ Raman spectroelectrochemical study of 13C labeled fullerene peapods and double walled carbon nanotubes (en)
  • In situ Raman spektroelektrochemická studie fullerenových peapodů a dvojstěnných uhlíkových nanotub obsahující uhlík 13C (cs)
skos:prefLabel
  • In situ Raman spectroelectrochemical study of 13C labeled fullerene peapods and double walled carbon nanotubes
  • In situ Raman spectroelectrochemical study of 13C labeled fullerene peapods and double walled carbon nanotubes (en)
  • In situ Raman spektroelektrochemická studie fullerenových peapodů a dvojstěnných uhlíkových nanotub obsahující uhlík 13C (cs)
skos:notation
  • RIV/61388955:_____/07:00090797!RIV08-MSM-61388955
http://linked.open.../vavai/riv/strany
  • 1746;1752
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(KJB400400601), P(LC510), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika
  • 10
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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http://linked.open...dnocenehoVysledku
  • 425841
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/07:00090797
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Raman spectroscopy; spectroelectrochemistry; carbon nanotube (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [4B12A4A83EA3]
http://linked.open...i/riv/nazevZdroje
  • Small
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http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 3
http://linked.open...iv/tvurceVysledku
  • Dunsch, L.
  • Kalbáč, Martin
  • Kavan, Ladislav
  • Zukalová, Markéta
http://linked.open...n/vavai/riv/zamer
issn
  • 1613-6810
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