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| rdf:type
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| Description
| - Vysoce rozlišená infračervená spektra s Fourierovou trasformací v oblasti mezi 1235 a 1680 cm-1 a subterahertzová spektra v oblasti mezi 250 a 630 GHz izotopicky čistého vzorku 13CH3 35Cl byla změřena a simultánně analyzována se zahrnutím všech důležitých interakcí v systému vibračních hladin v2 = 1, v5 = 1, and v3 = 2. Přechody odpovídaící několika .alpha.-rezonancím, generujícím tzv. poruchou povolené přechody, byly zaznamenány jak ve vibračně-rotačních tak čistě rotačních spektrech. Toto umožnilo přesné a vzájemně nezávislé určení konstant Ao = 5.2057469 (55) cm-1 a = 8.4404 (84) x 10-5 cm-1. I přes korelaci s vyššími členy rezonancí .alpha. byla určena i konstanta = 8.527 (39) x 10-9 cm-1. S pomocí 51 nastavitelných parametrů bylo více než 5800 infračervených a 550 rotačních dat popsáno v rámci jejich experimentální přesnosti. (cs)
- High-resolution Fourier-transform infrared spectra between 1235 and 1680 cm(-1) and subterahertz spectra between 250 and 630 GHz of monoisotopic (CH3Cl)-C-13-Cl-35 have been recorded and analyzed simultaneously, with all Coriolis, a-resonance, and l-type interactions in the polyad of the v(2) = 1, v(5) = 1, and v(3) = 2 levels taken into account. Several a-resonances (Delta k =+/- 2, Delta/ = T -/+ 1) generating perturbation-allowed transitions have been assigned in the rovibrational spectra. These resonances enabled us to determine accurately and independently the ground state rotational and centrifugal distortion parameters A(0) = 5.205 746 9 (55) cm(-1) and D-K(0) = 8.4404(84) x 10(-5) cm(-1). Even H-K(0) = 8.527(39) x 10(-9) cm(-1), which is, however, correlated to higher-order g-resonance terms, was determined. With 51 upper state parameters varied, about 5800 rovibrational wavenumbers and more than 550 rotational frequencies pertaining ...
- High-resolution Fourier-transform infrared spectra between 1235 and 1680 cm(-1) and subterahertz spectra between 250 and 630 GHz of monoisotopic (CH3Cl)-C-13-Cl-35 have been recorded and analyzed simultaneously, with all Coriolis, a-resonance, and l-type interactions in the polyad of the v(2) = 1, v(5) = 1, and v(3) = 2 levels taken into account. Several a-resonances (Delta k =+/- 2, Delta/ = T -/+ 1) generating perturbation-allowed transitions have been assigned in the rovibrational spectra. These resonances enabled us to determine accurately and independently the ground state rotational and centrifugal distortion parameters A(0) = 5.205 746 9 (55) cm(-1) and D-K(0) = 8.4404(84) x 10(-5) cm(-1). Even H-K(0) = 8.527(39) x 10(-9) cm(-1), which is, however, correlated to higher-order g-resonance terms, was determined. With 51 upper state parameters varied, about 5800 rovibrational wavenumbers and more than 550 rotational frequencies pertaining ... (en)
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| Title
| - High-resolution infrared and subterahertz spectroscopy of the v(2)=1, v(5)=1, and v(3)=2 levels of (CH3)-C-13 Cl-35
- High-resolution infrared and subterahertz spectroscopy of the v(2)=1, v(5)=1, and v(3)=2 levels of (CH3)-C-13 Cl-35 (en)
- Vysoce rozlišená infračervená a subterahertzová spektroskopie hladin v2 = 1, v5 = 1 a v3 = 2 molekuly 13CH3 35Cl (cs)
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| skos:prefLabel
| - High-resolution infrared and subterahertz spectroscopy of the v(2)=1, v(5)=1, and v(3)=2 levels of (CH3)-C-13 Cl-35
- High-resolution infrared and subterahertz spectroscopy of the v(2)=1, v(5)=1, and v(3)=2 levels of (CH3)-C-13 Cl-35 (en)
- Vysoce rozlišená infračervená a subterahertzová spektroskopie hladin v2 = 1, v5 = 1 a v3 = 2 molekuly 13CH3 35Cl (cs)
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| skos:notation
| - RIV/61388955:_____/07:00087924!RIV08-MSM-61388955
|
| http://linked.open.../vavai/riv/strany
| |
| http://linked.open...avai/riv/aktivita
| |
| http://linked.open...avai/riv/aktivity
| - P(1ET400400410), P(IAA400400504), P(LC06071), Z(AV0Z40400503)
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| http://linked.open...iv/cisloPeriodika
| |
| http://linked.open...vai/riv/dodaniDat
| |
| http://linked.open...aciTvurceVysledku
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| http://linked.open.../riv/druhVysledku
| |
| http://linked.open...iv/duvernostUdaju
| |
| http://linked.open...titaPredkladatele
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| http://linked.open...dnocenehoVysledku
| |
| http://linked.open...ai/riv/idVysledku
| - RIV/61388955:_____/07:00087924
|
| http://linked.open...riv/jazykVysledku
| |
| http://linked.open.../riv/klicovaSlova
| - simultaneous revibrational analysis; vibration-rotation bands; methyl-chloride (en)
|
| http://linked.open.../riv/klicoveSlovo
| |
| http://linked.open...odStatuVydavatele
| - US - Spojené státy americké
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| http://linked.open...ontrolniKodProRIV
| |
| http://linked.open...i/riv/nazevZdroje
| - Journal of Molecular Spectroscopy
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| http://linked.open...in/vavai/riv/obor
| |
| http://linked.open...ichTvurcuVysledku
| |
| http://linked.open...cetTvurcuVysledku
| |
| http://linked.open...vavai/riv/projekt
| |
| http://linked.open...UplatneniVysledku
| |
| http://linked.open...v/svazekPeriodika
| |
| http://linked.open...iv/tvurceVysledku
| - Pracna, Petr
- Burger, H.
- Demaison, J.
- Litz, M.
- Constantin, F. L.
- Féjard, L.
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| http://linked.open...n/vavai/riv/zamer
| |
| issn
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| number of pages
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| is http://linked.open...avai/riv/vysledek
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