About: Electrodeposited Mesoporous ZnO Thin Films as Efficient Photocatalysts for the degradation of dye pollutants     Goto   Sponge   NotDistinct   Permalink

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  • Tenké mesoporézní filmy ZnO byly připraveny elektrochemickou metodou využívající eosin Y jako činidla řídícího strukturu. Porézní filmy ZnO byly získány odstraněním eosinu ze struktury. Velikost jejich povrchu a mesoporozita byly charakterizovány fyzikální adsorpcí kryptonu. Parametry depozice, jako její délka a koncentrace eosinu v roztoku, byly optimalizovány, aby byly získány filmy s co možná největším povrchem tak i dobrými mechanickými vlastnostmi. Nejlepší kompromis byl nalezen pro filmy, jejichž tloušťka dosahuje 2 až 3 mikrometry a jež byly připraveny s koncentrací eosinu 50-60 mikroM. Fotodegradace heteropolyaromatického barviva methylenové modře a diazobarviva kongo červeně sloužily jako modelové reakce pro studium fotokatalytické aktivity filmů. Bylo zjištěno, rychlost fotodegradace pro obě barviva dosahuje maxima pro mesoporézní filmy připravené s koncentrací eosinu nad 40 mikroM. (cs)
  • Thin mesoporous films of ZnO were prepared by electrochemical deposition using eosin Y as a structure-directing agent. After removal of the eosin from the structure, transparent porous ZnO films were obtained. The porosity and surface area of these films were determined by performing krypton BET measurements. Electrochemical deposition parameters, such as the deposition time and the eosin concentration in the plating bath, were optimized to prepare films with large internal surface areas and good mechanical properties. Eosin concentrations of 50-60 M were found to give the best-quality mesoporous zinc oxide films with film thicknesses ranging from 2 to 3 m. The photodegradations of a heteropolyaromatic dye (methylene blue) and a diazo dye (congo red) served as model reactions to assess the photocatalytic activity of the zinc oxide films. For both dyes, the photodegradation rate reached its maximum for mesoporous films that were prepared with eosin concentrations above 40 M.
  • Thin mesoporous films of ZnO were prepared by electrochemical deposition using eosin Y as a structure-directing agent. After removal of the eosin from the structure, transparent porous ZnO films were obtained. The porosity and surface area of these films were determined by performing krypton BET measurements. Electrochemical deposition parameters, such as the deposition time and the eosin concentration in the plating bath, were optimized to prepare films with large internal surface areas and good mechanical properties. Eosin concentrations of 50-60 M were found to give the best-quality mesoporous zinc oxide films with film thicknesses ranging from 2 to 3 m. The photodegradations of a heteropolyaromatic dye (methylene blue) and a diazo dye (congo red) served as model reactions to assess the photocatalytic activity of the zinc oxide films. For both dyes, the photodegradation rate reached its maximum for mesoporous films that were prepared with eosin concentrations above 40 M. (en)
Title
  • Electrodeposited Mesoporous ZnO Thin Films as Efficient Photocatalysts for the degradation of dye pollutants
  • Electrodeposited Mesoporous ZnO Thin Films as Efficient Photocatalysts for the degradation of dye pollutants (en)
  • Tenké mesoporézní filmy ZnO připravené elektrodepozicí jako účinné fotokatalyzátory pro degradaci polutantů barviv (cs)
skos:prefLabel
  • Electrodeposited Mesoporous ZnO Thin Films as Efficient Photocatalysts for the degradation of dye pollutants
  • Electrodeposited Mesoporous ZnO Thin Films as Efficient Photocatalysts for the degradation of dye pollutants (en)
  • Tenké mesoporézní filmy ZnO připravené elektrodepozicí jako účinné fotokatalyzátory pro degradaci polutantů barviv (cs)
skos:notation
  • RIV/61388955:_____/07:00087868!RIV08-AV0-61388955
http://linked.open.../vavai/riv/strany
  • 7639;7644
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika
  • 21
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 419723
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/07:00087868
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • ZnO films; photocatalysis; pollutants (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [BE1F25FAB6B7]
http://linked.open...i/riv/nazevZdroje
  • Journal of Physical Chemistry C
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 111
http://linked.open...iv/tvurceVysledku
  • Rathouský, Jiří
  • Pauporté, T.
http://linked.open...n/vavai/riv/zamer
issn
  • 1932-7447
number of pages
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