| Attributes | Values |
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| rdf:type
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| Description
| - Kombinací modelování odpovídajících procesů v destičce katalyzátoru s multi spektroskopickými experimenty za dynamických podmínek je navržen nový kvantitativní přístup k in situ experimentům. Vypracovaná studie ukazuje potenciál přístupu detailní analýzy procesů v zeolitech s obsahem kovů; například adsorpce amoniaku na CoNa- FER, reakce selektivní katalytické redukce NO amoniakem a rozklad N2O na Fe-FER. Pro získání kvantitativních informacích o transportu, adsorpčně/desorpčních jevech a přeměně povrchových částic na zeolitickém systému obsahujícím ionty přechodných kovů za určitých podmínek je použita kombinace simultánní in situ FTIR a UV-Vis spektroskopie za přechodových podmínek a modelu reaktoru spektroskopické cely. (cs)
- A new quantitative approach to in situ experiments is proposed based on consistent combination of modeling of the relevant processes in the catalyst pellet with realization of the multi-spectroscopic experiment under dynamic regimes. Using well defined Co- and Fe-FER samples the approach is illustrated by three case studies showing potential of the approach for detail analysis of the processes over metallo-zeolites, i.e. adsorption of NH3 on CoNa-FER, and reactions of selective catalytic reduction of NO by NH3, and N2O decomposition over Fe-FER. Combination of simultaneous in situ FTIR and UV-Vis spectroscopies under transient conditions and a single-pellet reactor model of the spectroscopic cell are used for obtaining some quantitative information on the transport, adsorption/desorption phenomena, and surface species transformation over transition metal ion/zeolite system under such conditions.
- A new quantitative approach to in situ experiments is proposed based on consistent combination of modeling of the relevant processes in the catalyst pellet with realization of the multi-spectroscopic experiment under dynamic regimes. Using well defined Co- and Fe-FER samples the approach is illustrated by three case studies showing potential of the approach for detail analysis of the processes over metallo-zeolites, i.e. adsorption of NH3 on CoNa-FER, and reactions of selective catalytic reduction of NO by NH3, and N2O decomposition over Fe-FER. Combination of simultaneous in situ FTIR and UV-Vis spectroscopies under transient conditions and a single-pellet reactor model of the spectroscopic cell are used for obtaining some quantitative information on the transport, adsorption/desorption phenomena, and surface species transformation over transition metal ion/zeolite system under such conditions. (en)
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| Title
| - Simultaneous FTIR/UV-Vis study of reactions over metallo-zeolites. Approach to quantitative in situ studies
- Simultaneous FTIR/UV-Vis study of reactions over metallo-zeolites. Approach to quantitative in situ studies (en)
- Simultánní FTIR/UV-Vis studie reakcí na zeolitech s obsahem kovů. Přístup ke kvantitativním in situ studiím (cs)
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| skos:prefLabel
| - Simultaneous FTIR/UV-Vis study of reactions over metallo-zeolites. Approach to quantitative in situ studies
- Simultaneous FTIR/UV-Vis study of reactions over metallo-zeolites. Approach to quantitative in situ studies (en)
- Simultánní FTIR/UV-Vis studie reakcí na zeolitech s obsahem kovů. Přístup ke kvantitativním in situ studiím (cs)
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| skos:notation
| - RIV/61388955:_____/07:00081136!RIV08-AV0-61388955
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| http://linked.open.../vavai/riv/strany
| |
| http://linked.open...avai/riv/aktivita
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| http://linked.open...avai/riv/aktivity
| - P(1ET400400413), P(GA104/06/1254), P(GA203/05/2309), Z(AV0Z40400503)
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| http://linked.open...iv/cisloPeriodika
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| http://linked.open...vai/riv/dodaniDat
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| http://linked.open...aciTvurceVysledku
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| http://linked.open.../riv/druhVysledku
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| http://linked.open...iv/duvernostUdaju
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| http://linked.open...titaPredkladatele
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| http://linked.open...dnocenehoVysledku
| |
| http://linked.open...ai/riv/idVysledku
| - RIV/61388955:_____/07:00081136
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| http://linked.open...riv/jazykVysledku
| |
| http://linked.open.../riv/klicovaSlova
| - metallo-zeolites; FTIR/UV-Vis; adsorption; modeling; in-situ (en)
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| http://linked.open.../riv/klicoveSlovo
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| http://linked.open...odStatuVydavatele
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| http://linked.open...ontrolniKodProRIV
| |
| http://linked.open...i/riv/nazevZdroje
| |
| http://linked.open...in/vavai/riv/obor
| |
| http://linked.open...ichTvurcuVysledku
| |
| http://linked.open...cetTvurcuVysledku
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| http://linked.open...vavai/riv/projekt
| |
| http://linked.open...UplatneniVysledku
| |
| http://linked.open...v/svazekPeriodika
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| http://linked.open...iv/tvurceVysledku
| - Sobalík, Zdeněk
- Jíša, Kamil
- Jirglová, Hana
- Bernauer, B.
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| http://linked.open...n/vavai/riv/zamer
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| issn
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| number of pages
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| is http://linked.open...avai/riv/vysledek
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