About: Metathesis of linear .alpha.-olefins with MoO3 supported on MCM-41 catalyst     Goto   Sponge   NotDistinct   Permalink

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Description
  • New type of heterogeneous catalysts based on mesoporous molecular sieve MCM-41 modified with molybdenum oxide was proposed for the application in metathesis of linear 1-olefins. This catalyst prepared via %22thermal spreading method%22 operates in a liquid phase under ambient or slightly higher reaction temperature without the presence of solvent. The optimum loading of molybdenum oxide was 8 wt. % of Mo. For 1-octene, the conversion achieved in 390 min. at 40 oC was 74 %, and the selectivity to 14-tetradecene was 82 %.
  • New type of heterogeneous catalysts based on mesoporous molecular sieve MCM-41 modified with molybdenum oxide was proposed for the application in metathesis of linear 1-olefins. This catalyst prepared via %22thermal spreading method%22 operates in a liquid phase under ambient or slightly higher reaction temperature without the presence of solvent. The optimum loading of molybdenum oxide was 8 wt. % of Mo. For 1-octene, the conversion achieved in 390 min. at 40 oC was 74 %, and the selectivity to 14-tetradecene was 82 %. (en)
Title
  • Metathesis of linear .alpha.-olefins with MoO3 supported on MCM-41 catalyst
  • Metathesis of linear .alpha.-olefins with MoO3 supported on MCM-41 catalyst (en)
skos:prefLabel
  • Metathesis of linear .alpha.-olefins with MoO3 supported on MCM-41 catalyst
  • Metathesis of linear .alpha.-olefins with MoO3 supported on MCM-41 catalyst (en)
skos:notation
  • RIV/61388955:_____/05:00000711!RIV11-GA0-61388955
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GD203/03/H140), P(IAA4040411), Z(AV0Z40400503)
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 529686
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/05:00000711
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • heterogeneous catalyst; X-ray diffraction; catalytic reaction (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [8CC4326973D9]
http://linked.open...v/mistoKonaniAkce
  • Niagara Falls
http://linked.open...i/riv/mistoVydani
  • Amsterdam
http://linked.open...i/riv/nazevZdroje
  • Nanoporous Materials
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...iv/tvurceVysledku
  • Topka, Pavel
  • Čejka, Jiří
  • Balcar, Hynek
  • Žilková, Naděžda
  • Pérez-Pariente, J.
http://linked.open...vavai/riv/typAkce
http://linked.open.../riv/zahajeniAkce
http://linked.open...n/vavai/riv/zamer
number of pages
http://purl.org/ne...btex#hasPublisher
  • Elsevier
https://schema.org/isbn
  • 978-0-444-51748-7
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