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rdf:type
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Description
| - The title binaphthyls 19 and 26, which are the positional isomers of 2-methoxy-2 -(diphenylphosphino)-1,1 -binaphthyl (MOP, 19) and 2-amino-2 hydroxy-1,1 -binaphthyl (NOBIN,26), have been synthesized by Suzuki coupling as the key step (10+15-->18), followed by functional group transformations, involving C-P and C-N bond formation (18-19 and 18-23), Racemic intermediate 22 was resolved by cocrystallization with N-Benzylcinchonidinium chloride and the absolute configuration determined by X-ray crystallography.
- The title binaphthyls 19 and 26, which are the positional isomers of 2-methoxy-2 -(diphenylphosphino)-1,1 -binaphthyl (MOP, 19) and 2-amino-2 hydroxy-1,1 -binaphthyl (NOBIN,26), have been synthesized by Suzuki coupling as the key step (10+15-->18), followed by functional group transformations, involving C-P and C-N bond formation (18-19 and 18-23), Racemic intermediate 22 was resolved by cocrystallization with N-Benzylcinchonidinium chloride and the absolute configuration determined by X-ray crystallography. (en)
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Title
| - 2,8'-Disubstituted-1,1'-Binaphthyls: A New Pattern in Chiral Ligands.
- 2,8'-Disubstituted-1,1'-Binaphthyls: A New Pattern in Chiral Ligands. (en)
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skos:prefLabel
| - 2,8'-Disubstituted-1,1'-Binaphthyls: A New Pattern in Chiral Ligands.
- 2,8'-Disubstituted-1,1'-Binaphthyls: A New Pattern in Chiral Ligands. (en)
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skos:notation
| - RIV/61388955:_____/02:54020174!RIV/2003/AV0/A54003/N
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http://linked.open.../vavai/riv/strany
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(GA203/00/0601), P(GA203/00/0632), P(GA203/99/M037), Z(AV0Z4040901), Z(MSM 113100001)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61388955:_____/02:54020174
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - amination; chiral resolution; Suzuki coupling (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - DE - Spolková republika Německo
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Chemistry European Journal
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...ocetUcastnikuAkce
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http://linked.open...nichUcastnikuAkce
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Císařová, I.
- Kočovský, P.
- Polášek, Miroslav
- Tišlerová, I.
- Vyskočil, Š.
- Meca, L.
- Belokon, Y. N.
- Farrugia, L.
- Harutyunyan, S. R.
- Stead, R. M. J.
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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