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| Description
| - The results were presented at 2nd International Conference on Chemical Technology in Mikulov. The results describe the newly developed polymerization model, which enables the simulation of polypropylene homomatrix synthesis and its polymer properties. The polymerization model was developed on basis of a multidimensional regression analysis of experimental polymerization data. The experimental basis was relatively large, comprising the input parameters in the following ranges: TEA/ED molar ratio: 2 - 10 mol/mol, polymerization temperature T: 60 - 90°C, hydrogen concentration H2/C3: 3.5 - 60 mmol/mol. The polymerizations were performed in 2-L laboratory stainless steel reactor at the polymerization conditions comparable to typical industrial polymerization processes. We utilize the newly developed polymerization model in the following ways: 1) prediction of catalyst activity and polymer properties under specified polymerization conditions, 2) construction of catalyst activity and polymer properties trends under specified ranges of polymerization conditions (one or two variables – 2D or 3D trends), 3) searching for optimal polymerization conditions related with polymer properties of requested polypropylene matrix.
- The results were presented at 2nd International Conference on Chemical Technology in Mikulov. The results describe the newly developed polymerization model, which enables the simulation of polypropylene homomatrix synthesis and its polymer properties. The polymerization model was developed on basis of a multidimensional regression analysis of experimental polymerization data. The experimental basis was relatively large, comprising the input parameters in the following ranges: TEA/ED molar ratio: 2 - 10 mol/mol, polymerization temperature T: 60 - 90°C, hydrogen concentration H2/C3: 3.5 - 60 mmol/mol. The polymerizations were performed in 2-L laboratory stainless steel reactor at the polymerization conditions comparable to typical industrial polymerization processes. We utilize the newly developed polymerization model in the following ways: 1) prediction of catalyst activity and polymer properties under specified polymerization conditions, 2) construction of catalyst activity and polymer properties trends under specified ranges of polymerization conditions (one or two variables – 2D or 3D trends), 3) searching for optimal polymerization conditions related with polymer properties of requested polypropylene matrix. (en)
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| Title
| - MODELING OF SYNTHESIS AND POLYMER PROPERTIES OF HOMOPOLYMER POLYPROPYLENE MATRIX
- MODELING OF SYNTHESIS AND POLYMER PROPERTIES OF HOMOPOLYMER POLYPROPYLENE MATRIX (en)
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| skos:prefLabel
| - MODELING OF SYNTHESIS AND POLYMER PROPERTIES OF HOMOPOLYMER POLYPROPYLENE MATRIX
- MODELING OF SYNTHESIS AND POLYMER PROPERTIES OF HOMOPOLYMER POLYPROPYLENE MATRIX (en)
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| skos:notation
| - RIV/60711990:_____/14:#0000119!RIV14-MPO-60711990
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| http://linked.open...avai/predkladatel
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| http://linked.open...avai/riv/aktivita
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| http://linked.open...avai/riv/aktivity
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| http://linked.open...vai/riv/dodaniDat
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| http://linked.open...aciTvurceVysledku
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| http://linked.open.../riv/druhVysledku
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| http://linked.open...iv/duvernostUdaju
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| http://linked.open...titaPredkladatele
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| http://linked.open...dnocenehoVysledku
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| http://linked.open...ai/riv/idVysledku
| - RIV/60711990:_____/14:#0000119
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| http://linked.open...riv/jazykVysledku
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| http://linked.open.../riv/klicovaSlova
| - homopolymerization model; modeling of polypropylene synthesis; modeling of polypropylene properties (en)
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| http://linked.open.../riv/klicoveSlovo
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| http://linked.open...ontrolniKodProRIV
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| http://linked.open...in/vavai/riv/obor
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| http://linked.open...ichTvurcuVysledku
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| http://linked.open...cetTvurcuVysledku
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| http://linked.open...vavai/riv/projekt
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| http://linked.open...UplatneniVysledku
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| http://linked.open...iv/tvurceVysledku
| - Kratochvíla, Jan
- Grůza, Jan
|
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