About: Dipole moments of CH3F in the nu(3) and nu(6) vibrational excited states from the Stark effect     Goto   Sponge   NotDistinct   Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

AttributesValues
rdf:type
rdfs:seeAlso
Description
  • Both the parallel and perpendicular rotational Stark components of the methyl fluoride J, k, l: 2, +/- 1, 0 {- 1, +/- 1, 0 and 2, +/- 1, -/+ 1 {- 1, +/- 1, -/+ 1 lines in the nu(3) and nu(6) excited vibrational states were measured in the microwave region of ca 100 GHz at the Stark fields in the range of ca 150-1100 V/cm. The analysis of the Stark components was complicated by unexpected hyperfine structure patterns spanning a few MHz, which were observed for M-J components with large Stark shifts (} 300 MHz), most probably due to an enhancement through the Stark effect. The permanent electric dipole moments for these two vibrational states were derived from selected separated hyperfine components of the Stark components: mu(3)=1.90345(46) D, mu(6)=1.86394(32) 0 (the expanded uncertainties are given with the coverage factor k=2). The significant perturbational second-order Stark contributions were simply eliminated using a Stark component difference approach. Third-order Stark contributions were included in the analysis, and higher-order Stark contributions and polarizability contributions were neglected since they are inconsequential in this study.
  • Both the parallel and perpendicular rotational Stark components of the methyl fluoride J, k, l: 2, +/- 1, 0 {- 1, +/- 1, 0 and 2, +/- 1, -/+ 1 {- 1, +/- 1, -/+ 1 lines in the nu(3) and nu(6) excited vibrational states were measured in the microwave region of ca 100 GHz at the Stark fields in the range of ca 150-1100 V/cm. The analysis of the Stark components was complicated by unexpected hyperfine structure patterns spanning a few MHz, which were observed for M-J components with large Stark shifts (} 300 MHz), most probably due to an enhancement through the Stark effect. The permanent electric dipole moments for these two vibrational states were derived from selected separated hyperfine components of the Stark components: mu(3)=1.90345(46) D, mu(6)=1.86394(32) 0 (the expanded uncertainties are given with the coverage factor k=2). The significant perturbational second-order Stark contributions were simply eliminated using a Stark component difference approach. Third-order Stark contributions were included in the analysis, and higher-order Stark contributions and polarizability contributions were neglected since they are inconsequential in this study. (en)
Title
  • Dipole moments of CH3F in the nu(3) and nu(6) vibrational excited states from the Stark effect
  • Dipole moments of CH3F in the nu(3) and nu(6) vibrational excited states from the Stark effect (en)
skos:prefLabel
  • Dipole moments of CH3F in the nu(3) and nu(6) vibrational excited states from the Stark effect
  • Dipole moments of CH3F in the nu(3) and nu(6) vibrational excited states from the Stark effect (en)
skos:notation
  • RIV/60461373:22340/14:43897586!RIV15-GA0-22340___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GAP206/10/2182), P(GPP206/10/P481)
http://linked.open...iv/cisloPeriodika
  • Nov 2014
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 11626
http://linked.open...ai/riv/idVysledku
  • RIV/60461373:22340/14:43897586
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Hyperfine splitting enhanced through the Stark effect; Methyl fluoride; Vibrational excited states; Microwave spectroscopy; Dipole moment; Stark rotational combination differences (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [E57C88572E8E]
http://linked.open...i/riv/nazevZdroje
  • Journal of Quantitative Spectroscopy and Radiative Transfer
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 148
http://linked.open...iv/tvurceVysledku
  • Kania, Patrik
  • Urban, Štěpán
  • Koubek, Jindřich
http://linked.open...ain/vavai/riv/wos
  • 000342254100024
issn
  • 0022-4073
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.jqsrt.2014.07.006
http://localhost/t...ganizacniJednotka
  • 22340
Faceted Search & Find service v1.16.118 as of Jun 21 2024


Alternative Linked Data Documents: ODE     Content Formats:   [cxml] [csv]     RDF   [text] [turtle] [ld+json] [rdf+json] [rdf+xml]     ODATA   [atom+xml] [odata+json]     Microdata   [microdata+json] [html]    About   
This material is Open Knowledge   W3C Semantic Web Technology [RDF Data] Valid XHTML + RDFa
OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 123 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software