About: Heat capacity equations for nonstoichiometric solids

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An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The equations for heat capacity measured under isodynamical conditions (fixed activity of a single component) are derived for partly open systems exchanging one component with the surroundings while keeping the contents of all other components constant. Compared to conventional isobaric (and isoplethal) heat capacity of a strictly stoichiometric phase, the isodynamical heat capacity of a nonstoichiometric phase is found to involve two additional terms-the saturation contribution due to incorporation (or release) of the free component and the contribution due to deviation from stoichiometry reflecting a different number of the involved phonon modes (due to different free component content) and in some cases a variation of free component incorporation mechanism. The equations for heat capacity measured under isodynamical conditions (fixed activity of a single component) are derived for partly open systems exchanging one component with the surroundings while keeping the contents of all other components constant. Compared to conventional isobaric (and isoplethal) heat capacity of a strictly stoichiometric phase, the isodynamical heat capacity of a nonstoichiometric phase is found to involve two additional terms-the saturation contribution due to incorporation (or release) of the free component and the contribution due to deviation from stoichiometry reflecting a different number of the involved phonon modes (due to different free component content) and in some cases a variation of free component incorporation mechanism. (en)
Title	Heat capacity equations for nonstoichiometric solids Heat capacity equations for nonstoichiometric solids (en)
skos:prefLabel	Heat capacity equations for nonstoichiometric solids Heat capacity equations for nonstoichiometric solids (en)
skos:notation	RIV/60461373:22340/13:43897134!RIV15-MSM-22340___
http://linked.open...avai/riv/aktivita	I P
http://linked.open...avai/riv/aktivity	I, P(ED2.1.00/03.0088)
http://linked.open...iv/cisloPeriodika	1
http://linked.open...vai/riv/dodaniDat	2015
http://linked.open...aciTvurceVysledku	Sedmidubský, David
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoká škola chemicko-technologická v Praze / Fakulta chemicko-inženýrská
http://linked.open...dnocenehoVysledku	77148
http://linked.open...ai/riv/idVysledku	RIV/60461373:22340/13:43897134
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Nonstoichiometry; Partly open systems; Controlled atmosphere; Heat capacity (en)
http://linked.open.../riv/klicoveSlovo	Nonstoichiometry Heat capacity Controlled atmosphere Partly open systems
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[6A63E2491C0E]
http://linked.open...i/riv/nazevZdroje	Journal of Thermal Analysis and Calorimetry
http://linked.open...in/vavai/riv/obor	BJ
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	2 (xsd:int)
http://linked.open...vavai/riv/projekt	Centre of the New Technologies and Materials
http://linked.open...UplatneniVysledku	2013
http://linked.open...v/svazekPeriodika	113
http://linked.open...iv/tvurceVysledku	Sedmidubský, David Holba, P.
http://linked.open...ain/vavai/riv/wos	000321567800028
issn	1388-6150
number of pages	7 (xsd:int)
http://bibframe.org/vocab/doi	10.1007/s10973-012-2886-1
http://localhost/t...ganizacniJednotka	22340

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