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  • The wetting and filling properties of a fluid adsorbed on a solid grooved substrate are studied by means of a microscopic density functional theory. The grooved substrates are modelled using a solid slab, interacting with the fluid particles via long-range dispersion forces, to which a one-dimensional array of infinitely long rectangular grooves is sculpted. By investigating the effect of the groove periodicity and the width of the grooves and the ridges, a rich variety of different wetting morphologies is found. In particular, we show that for a saturated ambient gas, the adsorbent can occur in one of four wetting states characterized by (i) empty grooves, (ii) filled grooves, (iii) a formation of mesoscopic hemispherical caps (iv) a macroscopically wet surface. The character of the transition between particular regimes, that also extend off-coexistence, sensitively depends on the model geometry. The temperature at which the system becomes completely wet is considerably higher than that for a flat wall.
  • The wetting and filling properties of a fluid adsorbed on a solid grooved substrate are studied by means of a microscopic density functional theory. The grooved substrates are modelled using a solid slab, interacting with the fluid particles via long-range dispersion forces, to which a one-dimensional array of infinitely long rectangular grooves is sculpted. By investigating the effect of the groove periodicity and the width of the grooves and the ridges, a rich variety of different wetting morphologies is found. In particular, we show that for a saturated ambient gas, the adsorbent can occur in one of four wetting states characterized by (i) empty grooves, (ii) filled grooves, (iii) a formation of mesoscopic hemispherical caps (iv) a macroscopically wet surface. The character of the transition between particular regimes, that also extend off-coexistence, sensitively depends on the model geometry. The temperature at which the system becomes completely wet is considerably higher than that for a flat wall. (en)
Title
  • Filling and wetting transitions at grooved substrates
  • Filling and wetting transitions at grooved substrates (en)
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  • Filling and wetting transitions at grooved substrates
  • Filling and wetting transitions at grooved substrates (en)
skos:notation
  • RIV/60461373:22340/13:43895558!RIV14-GA0-22340___
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
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  • I, P(GA13-09914S)
http://linked.open...iv/cisloPeriodika
  • 44
http://linked.open...vai/riv/dodaniDat
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  • 74960
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  • RIV/60461373:22340/13:43895558
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  • FILMS; INTERFACE; ADSORPTION; CORRUGATION; CAPILLARY CONDENSATION; DENSITY-FUNCTIONAL THEORY (en)
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  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [33A1C4692621]
http://linked.open...i/riv/nazevZdroje
  • JOURNAL OF PHYSICS-CONDENSED MATTER
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  • 25
http://linked.open...iv/tvurceVysledku
  • Malijevský, Alexandr
http://linked.open...ain/vavai/riv/wos
  • 000325897900008
issn
  • 0953-8984
number of pages
http://bibframe.org/vocab/doi
  • 10.1088/0953-8984/25/44/445006
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  • 22340
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