About: Critical point wedge filling

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Description	We present results of a microscopic density functional theory study of wedge filling transitions, at a right-angle wedge, in the presence of dispersionlike wall-fluid forces. Far from the corner the walls of the wedge show a first-order wetting transition at a temperature Tw which is progressively closer to the bulk critical temperature Tc as the strength of the wall forces is reduced. In addition, the meniscus formed near the corner undergoes a filling transition at a temperature Tf {Tw, the value of which is found to be in excellent agreement with macroscopic predictions. We show that the filling transition is first order if it occurs far from the critical point but is continuous if Tf is close to Tc even though the walls still show firstorder wetting behavior. We present results of a microscopic density functional theory study of wedge filling transitions, at a right-angle wedge, in the presence of dispersionlike wall-fluid forces. Far from the corner the walls of the wedge show a first-order wetting transition at a temperature Tw which is progressively closer to the bulk critical temperature Tc as the strength of the wall forces is reduced. In addition, the meniscus formed near the corner undergoes a filling transition at a temperature Tf {Tw, the value of which is found to be in excellent agreement with macroscopic predictions. We show that the filling transition is first order if it occurs far from the critical point but is continuous if Tf is close to Tc even though the walls still show firstorder wetting behavior. (en)
Title	Critical point wedge filling Critical point wedge filling (en)
skos:prefLabel	Critical point wedge filling Critical point wedge filling (en)
skos:notation	RIV/60461373:22340/13:43895555!RIV14-GA0-22340___
http://linked.open...avai/predkladatel	Fakulta chemicko-inženýrská
http://linked.open...avai/riv/aktivita	P
http://linked.open...avai/riv/aktivity	P(GA13-09914S)
http://linked.open...iv/cisloPeriodika	16
http://linked.open...vai/riv/dodaniDat	2014
http://linked.open...aciTvurceVysledku	Malijevský, Alexandr
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoká škola chemicko-technologická v Praze / Fakulta chemicko-inženýrská
http://linked.open...dnocenehoVysledku	67317
http://linked.open...ai/riv/idVysledku	RIV/60461373:22340/13:43895555
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Wedge filling, critical point, density functional theory (en)
http://linked.open.../riv/klicoveSlovo	Wedge filling density functional theory critical point
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[B3D33B4F2B30]
http://linked.open...i/riv/nazevZdroje	Physical Review Letters
http://linked.open...in/vavai/riv/obor	BE
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	2 (xsd:int)
http://linked.open...vavai/riv/projekt	A controlling of diffusion processes in pores with varying permeability
http://linked.open...UplatneniVysledku	2013
http://linked.open...v/svazekPeriodika	110
http://linked.open...iv/tvurceVysledku	Malijevský, Alexandr Parry, Andrew
http://linked.open...ain/vavai/riv/wos	000317813800002
issn	0031-9007
number of pages	5 (xsd:int)
http://bibframe.org/vocab/doi	10.1103/PhysRevLett.110.166101
http://localhost/t...ganizacniJednotka	22340

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