About: Nonaqueous Capillary Electrophoretic Enantioseparation of Water Insoluble Troger's Base Derivatives Using beta-Cyclodextrin as Chiral Selector

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About: Nonaqueous Capillary Electrophoretic Enantioseparation of Water Insoluble Troger's Base Derivatives Using beta-Cyclodextrin as Chiral Selector Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://onlinelibrary.wiley.com/doi/10.1002/chir.22220/abstract
Description	Racemic mixtures of six Troger's base derivatives were separated by chiral nonaqueous capillary electrophoresis. The separation protocol was optimized first for suitable solvents. Then the applicability of various salts dissolved in organic solvents and their mixtures was evaluated. As chiral selectors -cyclodextrin and heptakis(2,6-di-O-methyl)--cyclodextrin at various concentrations were used. The best enantioselectivity for the studied analytes was obtained utilizing formamide as organic nonaqueous solvent containing a mixture of sodium citrate and tris(hydroxymethyl)aminomethane acetate as electrolytes, and -cyclodextrin as chiral additive. The experimental results demonstrated the feasibility of nonaqueous capillary electrophoresis for enantioseparation of Troger's base derivatives. This technique represents a suitable alternative to more commonly used capillary electrophoresis in aqueous environment. Chirality 25:810-813, 2013. (c) 2013 Wiley Periodicals, Inc. Racemic mixtures of six Troger's base derivatives were separated by chiral nonaqueous capillary electrophoresis. The separation protocol was optimized first for suitable solvents. Then the applicability of various salts dissolved in organic solvents and their mixtures was evaluated. As chiral selectors -cyclodextrin and heptakis(2,6-di-O-methyl)--cyclodextrin at various concentrations were used. The best enantioselectivity for the studied analytes was obtained utilizing formamide as organic nonaqueous solvent containing a mixture of sodium citrate and tris(hydroxymethyl)aminomethane acetate as electrolytes, and -cyclodextrin as chiral additive. The experimental results demonstrated the feasibility of nonaqueous capillary electrophoresis for enantioseparation of Troger's base derivatives. This technique represents a suitable alternative to more commonly used capillary electrophoresis in aqueous environment. Chirality 25:810-813, 2013. (c) 2013 Wiley Periodicals, Inc. (en)
Title	Nonaqueous Capillary Electrophoretic Enantioseparation of Water Insoluble Troger's Base Derivatives Using beta-Cyclodextrin as Chiral Selector Nonaqueous Capillary Electrophoretic Enantioseparation of Water Insoluble Troger's Base Derivatives Using beta-Cyclodextrin as Chiral Selector (en)
skos:prefLabel	Nonaqueous Capillary Electrophoretic Enantioseparation of Water Insoluble Troger's Base Derivatives Using beta-Cyclodextrin as Chiral Selector Nonaqueous Capillary Electrophoretic Enantioseparation of Water Insoluble Troger's Base Derivatives Using beta-Cyclodextrin as Chiral Selector (en)
skos:notation	RIV/60461373:22340/13:43895230!RIV14-GA0-22340___
http://linked.open...avai/predkladatel	Fakulta chemicko-inženýrská
http://linked.open...avai/riv/aktivita	P
http://linked.open...avai/riv/aktivity	P(GAP206/12/0453)
http://linked.open...iv/cisloPeriodika	11
http://linked.open...vai/riv/dodaniDat	2014
http://linked.open...aciTvurceVysledku	Novotný, Michal Král, Vladimír Sýkora, David Řezanka, Pavel Havlík, Martin
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoká škola chemicko-technologická v Praze / Fakulta chemicko-inženýrská
http://linked.open...dnocenehoVysledku	91903
http://linked.open...ai/riv/idVysledku	RIV/60461373:22340/13:43895230
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Troger's base; capillary electrophoresis; nonaqueous; enantioseparation; beta-cyclodextrin; capillary electrophoresis (en)
http://linked.open.../riv/klicoveSlovo	enantioseparation nonaqueous Troger's base beta-cyclodextrin capillary electrophoresis
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[07A7CC81A2FF]
http://linked.open...i/riv/nazevZdroje	Chirality
http://linked.open...in/vavai/riv/obor	CB
http://linked.open...ichTvurcuVysledku	5 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...vavai/riv/projekt	Affinity capillary electromigration methods for selective nanoanalysis of biomolecules and investigation of their interactions
http://linked.open...UplatneniVysledku	2013
http://linked.open...v/svazekPeriodika	25
http://linked.open...iv/tvurceVysledku	Král, Vladimír Novotný, Michal Sýkora, David Havlík, Martin Řezanka, Pavel
http://linked.open...ain/vavai/riv/wos	000326291700020
issn	0899-0042
number of pages	4 (xsd:int)
http://bibframe.org/vocab/doi	10.1002/chir.22220
http://localhost/t...ganizacniJednotka	22340

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