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  • This paper studies a method of estimating the kinetic parameters for wood thermal decomposition as an input for pyrolysis modelling. Samples of birch and pine wood were firstly examined using Thermogravimetric analysis (TG) both in oxidative (air) and non-oxidative (nitrogen) atmosphere, studying the influence of the heating rate (5, 15, 25 °C?min-1) on the wood mass loss rate. For a single step thermal degradation reaction in non-oxidative atmosphere activation energy and preexponential factor was determined from experimental data using isoconversional method. The results were used as initial estimates for optimization technique - genetic algorithm (GA). Using GA, three thermal degradation schemes of wood were studied. GA was proved to be effective tool for estimating kinetic parameters of pyrolysis models. Contrary to isoconversional method GA does not require user's participation during the parameter estimation process and is able to handle several parameters at once.
  • This paper studies a method of estimating the kinetic parameters for wood thermal decomposition as an input for pyrolysis modelling. Samples of birch and pine wood were firstly examined using Thermogravimetric analysis (TG) both in oxidative (air) and non-oxidative (nitrogen) atmosphere, studying the influence of the heating rate (5, 15, 25 °C?min-1) on the wood mass loss rate. For a single step thermal degradation reaction in non-oxidative atmosphere activation energy and preexponential factor was determined from experimental data using isoconversional method. The results were used as initial estimates for optimization technique - genetic algorithm (GA). Using GA, three thermal degradation schemes of wood were studied. GA was proved to be effective tool for estimating kinetic parameters of pyrolysis models. Contrary to isoconversional method GA does not require user's participation during the parameter estimation process and is able to handle several parameters at once. (en)
Title
  • Measurement and evaluation of experimental data for modelling thermal decomposition of solid materials
  • Measurement and evaluation of experimental data for modelling thermal decomposition of solid materials (en)
skos:prefLabel
  • Measurement and evaluation of experimental data for modelling thermal decomposition of solid materials
  • Measurement and evaluation of experimental data for modelling thermal decomposition of solid materials (en)
skos:notation
  • RIV/60461373:22340/12:43894162!RIV13-MSM-22340___
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • S
http://linked.open...iv/cisloPeriodika
  • 2012
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 148837
http://linked.open...ai/riv/idVysledku
  • RIV/60461373:22340/12:43894162
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • isoconversional method, optimization, fire modelling; TGA; genetic algorithm (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • IT - Italská republika
http://linked.open...ontrolniKodProRIV
  • [618F43680CF0]
http://linked.open...i/riv/nazevZdroje
  • Chemical Engineering Transactions
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 29
http://linked.open...iv/tvurceVysledku
  • Jahoda, Milan
  • Hasalová, Lucie
  • Ira, Jiří
issn
  • 1974-9791
number of pages
http://bibframe.org/vocab/doi
  • 10.3303/CET1229235
http://localhost/t...ganizacniJednotka
  • 22340
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