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  • Chiroptical spectroscopies are a useful tool with applications in absolute configuration determination, in conformational analysis, in the investigation of supermolecular organization and in high sensitivity studies of spatial arrangement of nearly any chiral system. These methods, circular dichroism (CD) spectroscopy and optical rotatory dispersion (observed as optical rotation if the experiment is carried out at a single wavelength) are chiral variants of absorption spectroscopy and refractive index measurement. The information about structure is encoded in the positions, signs and magnitudes of spectral bands. Electronic and vibrational circular dichroism spectroscopies are complementary. While the technique of electronic circular dichroism tends to see the molecule as a whole and provides chiral information via chromophores and their properties, vibrational circular dichroism is a more local phenomenon. As a rule, each bond in the molecule is a vibrational chromophore and we can get very detailed and local information from vibrational circular dichroism.
  • Chiroptical spectroscopies are a useful tool with applications in absolute configuration determination, in conformational analysis, in the investigation of supermolecular organization and in high sensitivity studies of spatial arrangement of nearly any chiral system. These methods, circular dichroism (CD) spectroscopy and optical rotatory dispersion (observed as optical rotation if the experiment is carried out at a single wavelength) are chiral variants of absorption spectroscopy and refractive index measurement. The information about structure is encoded in the positions, signs and magnitudes of spectral bands. Electronic and vibrational circular dichroism spectroscopies are complementary. While the technique of electronic circular dichroism tends to see the molecule as a whole and provides chiral information via chromophores and their properties, vibrational circular dichroism is a more local phenomenon. As a rule, each bond in the molecule is a vibrational chromophore and we can get very detailed and local information from vibrational circular dichroism. (en)
Title
  • Circular Dichrosim Spectroscopy
  • Circular Dichrosim Spectroscopy (en)
skos:prefLabel
  • Circular Dichrosim Spectroscopy
  • Circular Dichrosim Spectroscopy (en)
skos:notation
  • RIV/60461373:22340/12:43894041!RIV13-GA0-22340___
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
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  • P(GAP206/11/0836)
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 127245
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  • RIV/60461373:22340/12:43894041
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  • circular dichroism, methodology (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [5C030F86BC78]
http://linked.open...i/riv/mistoVydani
  • Weinheim
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  • Analytilcal Methods in Supramolecular Chemistry
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  • Maloň, Petr
  • Urbanová, Marie
number of pages
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  • Wiley-VCH Verlag & Co. KGaA
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  • 978-3-527-32982-3
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  • 22340
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