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Description
  • In this study, we present a model for the kinetics of multiple overlapping reactions. Mathematical representation of the kinetics of gas-evolving reactions is crucial for the modeling of the feed-to-glass conversion in a waste-glass melter. The model simulates multiple gas-evolving reactions that occur during heating of a high-alumina high-level waste melter feed. To obtain satisfactory kinetic parameters, we employed Kissinger's method combined with least-squares analysis. The nth-order reaction kinetics with variable reaction order sufficed for obtaining excellent agreement with measured thermogravimetric analysis data.
  • In this study, we present a model for the kinetics of multiple overlapping reactions. Mathematical representation of the kinetics of gas-evolving reactions is crucial for the modeling of the feed-to-glass conversion in a waste-glass melter. The model simulates multiple gas-evolving reactions that occur during heating of a high-alumina high-level waste melter feed. To obtain satisfactory kinetic parameters, we employed Kissinger's method combined with least-squares analysis. The nth-order reaction kinetics with variable reaction order sufficed for obtaining excellent agreement with measured thermogravimetric analysis data. (en)
Title
  • Melting of glass batch: Model for multiple overlapping gas-evolving reactions
  • Melting of glass batch: Model for multiple overlapping gas-evolving reactions (en)
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  • Melting of glass batch: Model for multiple overlapping gas-evolving reactions
  • Melting of glass batch: Model for multiple overlapping gas-evolving reactions (en)
skos:notation
  • RIV/60461373:22340/12:43893752!RIV13-GA0-22340___
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GAP106/11/1069)
http://linked.open...iv/cisloPeriodika
  • NEUVEDEN
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
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http://linked.open...titaPredkladatele
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  • 149292
http://linked.open...ai/riv/idVysledku
  • RIV/60461373:22340/12:43893752
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • TGA; Glass batch; Glass melting; Kissinger method; Reaction kinetics; Overlapping reactions (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [4E3979855BF7]
http://linked.open...i/riv/nazevZdroje
  • Thermochimica Acta
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http://linked.open...ichTvurcuVysledku
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 541
http://linked.open...iv/tvurceVysledku
  • Pokorný, Richard
  • Hrma, Pavel
  • Pierce, David A.
http://linked.open...ain/vavai/riv/wos
  • 000306253800002
issn
  • 0040-6031
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.tca.2012.04.019
http://localhost/t...ganizacniJednotka
  • 22340
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