About: Heat capacity, enthalpy and entropy of SrBi2O4 and Sr2Bi2O5     Goto   Sponge   NotDistinct   Permalink

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  • Heat capacity and enthalpy increments of ternary strontium bismuth(III) oxides SrBi2O4 and Sr2Bi2O5 were measured by the relaxation time method (2-210 K), DSC (253-352 K) and drop calorimetry (570-1072 K). Temperature dependencies of the molar heat capacity in the form Cpm=161.97+45.936e?3 T - 1.7862e6/T2 JK?1mol?1 and Cpm=197.48+87.463e?3 T - 1.9282e6/T2 JK?1mol?1 for SrBi2O4 and Sr2Bi2O5, respectively, were derived by the least-squares method from the experimental data. The molar entropies at 298.15 K, S°m(298.15 K)=206.1+-1.1 JK?1mol?1 for SrBi2O4 and S°m(298.15 K)=261.2+-1.4 JK?1mol?1 for Sr2Bi2O5, were evaluated from the low temperature heat capacity measurements.
  • Heat capacity and enthalpy increments of ternary strontium bismuth(III) oxides SrBi2O4 and Sr2Bi2O5 were measured by the relaxation time method (2-210 K), DSC (253-352 K) and drop calorimetry (570-1072 K). Temperature dependencies of the molar heat capacity in the form Cpm=161.97+45.936e?3 T - 1.7862e6/T2 JK?1mol?1 and Cpm=197.48+87.463e?3 T - 1.9282e6/T2 JK?1mol?1 for SrBi2O4 and Sr2Bi2O5, respectively, were derived by the least-squares method from the experimental data. The molar entropies at 298.15 K, S°m(298.15 K)=206.1+-1.1 JK?1mol?1 for SrBi2O4 and S°m(298.15 K)=261.2+-1.4 JK?1mol?1 for Sr2Bi2O5, were evaluated from the low temperature heat capacity measurements. (en)
Title
  • Heat capacity, enthalpy and entropy of SrBi2O4 and Sr2Bi2O5
  • Heat capacity, enthalpy and entropy of SrBi2O4 and Sr2Bi2O5 (en)
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  • Heat capacity, enthalpy and entropy of SrBi2O4 and Sr2Bi2O5
  • Heat capacity, enthalpy and entropy of SrBi2O4 and Sr2Bi2O5 (en)
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  • RIV/60461373:22340/12:43893700!RIV13-GA0-22340___
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
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  • P(GA203/09/1036), P(GAP108/10/1006), Z(MSM0021620834), Z(MSM6046137302), Z(MSM6046137307)
http://linked.open...iv/cisloPeriodika
  • 11.1.2012
http://linked.open...vai/riv/dodaniDat
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  • 138729
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  • RIV/60461373:22340/12:43893700
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  • Strontium bismuth(III) oxides; Calorimetry; Entropy; Enthalpy increments; Heat capacity (en)
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  • NL - Nizozemsko
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  • [EF4D53A5BAEF]
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  • Thermochimica Acta
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  • 531
http://linked.open...iv/tvurceVysledku
  • Růžička, Květoslav
  • Svoboda, Pavel
  • Leitner, Jindřich
  • Sedmidubský, David
http://linked.open...ain/vavai/riv/wos
  • 000301309700010
http://linked.open...n/vavai/riv/zamer
issn
  • 0040-6031
number of pages
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  • 10.1016/j.tca.2012.01.002
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  • 22340
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