About: Selective formation of either Tröger's base or spiro Tröger's base derivatives from [2-aminoporphyrinato(2-)]nickel by choice of reaction conditions

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About: Selective formation of either Tröger's base or spiro Tröger's base derivatives from [2-aminoporphyrinato(2-)]nickel by choice of reaction conditions Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The article reports on the unique manipulation of the acid-catalyzed reaction of [2-aminoporphyrinato(2-)]nickel with formaldehyde to form selectively either the symmetric Tröger's base or the asymmetric spiro Tröger's base bis(metalloporphyrin) derivative. The reaction is driven by the choice of acid catalyst, formaldehyde source, and particularly, solvent, to give a mixture of both derivatives in preparative yields of about 90%, or to give selectively one of the derivatives in a yield of about 60%. The article reports on the unique manipulation of the acid-catalyzed reaction of [2-aminoporphyrinato(2-)]nickel with formaldehyde to form selectively either the symmetric Tröger's base or the asymmetric spiro Tröger's base bis(metalloporphyrin) derivative. The reaction is driven by the choice of acid catalyst, formaldehyde source, and particularly, solvent, to give a mixture of both derivatives in preparative yields of about 90%, or to give selectively one of the derivatives in a yield of about 60%. (en)
Title	Selective formation of either Tröger's base or spiro Tröger's base derivatives from [2-aminoporphyrinato(2-)]nickel by choice of reaction conditions Selective formation of either Tröger's base or spiro Tröger's base derivatives from [2-aminoporphyrinato(2-)]nickel by choice of reaction conditions (en)
skos:prefLabel	Selective formation of either Tröger's base or spiro Tröger's base derivatives from [2-aminoporphyrinato(2-)]nickel by choice of reaction conditions Selective formation of either Tröger's base or spiro Tröger's base derivatives from [2-aminoporphyrinato(2-)]nickel by choice of reaction conditions (en)
skos:notation	RIV/60461373:22340/12:43893420!RIV13-GA0-22340___
http://linked.open...avai/predkladatel	Fakulta chemicko-inženýrská
http://linked.open...avai/riv/aktivita	P
http://linked.open...avai/riv/aktivity	P(GA203/08/1445)
http://linked.open...iv/cisloPeriodika	45
http://linked.open...vai/riv/dodaniDat	2013
http://linked.open...aciTvurceVysledku	Král, Vladimír Dolenský, Bohumil Tatar, Ameneh
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoká škola chemicko-technologická v Praze / Fakulta chemicko-inženýrská
http://linked.open...dnocenehoVysledku	167319
http://linked.open...ai/riv/idVysledku	RIV/60461373:22340/12:43893420
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Selectivity; Solvent effect; Spiro Tröger's base derivative; Tröger's base derivative; Bis(metalloporphyrin) (en)
http://linked.open.../riv/klicoveSlovo	Solvent effect Bis(metalloporphyrin) Spiro Tröger's base derivative Tröger's base derivative Selectivity
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[1E6DE00CE856]
http://linked.open...i/riv/nazevZdroje	Tetrahedron Letters
http://linked.open...in/vavai/riv/obor	CB
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...vavai/riv/projekt	Functional Molecular Tweezers Based on Bis Tröger's Bases
http://linked.open...UplatneniVysledku	2012
http://linked.open...v/svazekPeriodika	53
http://linked.open...iv/tvurceVysledku	Král, Vladimír Dvořáková, Hana Dolenský, Bohumil Tatar, Ameneh
http://linked.open...ain/vavai/riv/wos	000310760800009
issn	0040-4039
number of pages	3 (xsd:int)
http://bibframe.org/vocab/doi	10.1016/j.tetlet.2012.08.097
http://localhost/t...ganizacniJednotka	22340
is http://linked.open...avai/riv/vysledek of	Selective formation of either Tröger's base or spiro Tröger's base derivatives from [2-aminoporphyrinato(2-)]nickel by choice of reaction conditions

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