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  • A three-way catalytic converter is the most common reactor for detoxification of automobile exhaust gases. A detailed kinetic reaction scheme including over 20 reaction steps has been proposed for the catalytic oxidation of CO and unburned hydrocarbons, and simultaneous NOx reduction. We report results of the stoichiometric network analysis for the whole network of this reaction mechanism. Dominant oscillators determine positive and negative feedback loops, which cause the oscillatory behaviour within certain regions of parameters in bifurcation diagrams determined by numerical continuation techniques.
  • A three-way catalytic converter is the most common reactor for detoxification of automobile exhaust gases. A detailed kinetic reaction scheme including over 20 reaction steps has been proposed for the catalytic oxidation of CO and unburned hydrocarbons, and simultaneous NOx reduction. We report results of the stoichiometric network analysis for the whole network of this reaction mechanism. Dominant oscillators determine positive and negative feedback loops, which cause the oscillatory behaviour within certain regions of parameters in bifurcation diagrams determined by numerical continuation techniques. (en)
Title
  • Dominant oscillators in the reaction mechanism of a three way catalytic converter
  • Dominant oscillators in the reaction mechanism of a three way catalytic converter (en)
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  • Dominant oscillators in the reaction mechanism of a three way catalytic converter
  • Dominant oscillators in the reaction mechanism of a three way catalytic converter (en)
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  • RIV/60461373:22340/11:43891845!RIV12-MSM-22340___
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  • P(GA203/09/2091), P(GD104/08/H055), Z(MSM6046137306)
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  • 195256
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  • RIV/60461373:22340/11:43891845
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  • autocatalysis; oscillations; stoichiometric network analysis; three-way catalytic converter (en)
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  • [56DF970E6CC1]
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  • Roztoky u Křivoklátu
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  • Praha
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  • Workshop Reakční a transportní jevy V
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  • Schreiber, Igor
  • Hadač, Otto
  • Kubíček, Milan
  • Marek, Miloš
  • Nevoral, Vladislav
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number of pages
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  • Vysoká škola chemicko-technologická v Praze
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  • 978-80-7080-797-2
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  • 22340
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