About: Fourier-transform microwave and submillimeter-wave spectroscopy of chloroiodomethane, CH(2)ICl

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Guided by a previous microwave study (9-35 GHz), the rotational spectrum of both chlorine isotopologues of chloroiodomethane in its vibrational and electronic ground state has been re-investigated in the microwave region and extended to the millimeter/submillimeter-wave region. Weak a-type transitions have been recorded by Fourier transform microwave spectroscopy below 20 GHz whilst strong b-type rotational transitions have been recorded between 15 and 646 GHz, corresponding to energy levels with J '' {= 108 and K(a)'' {= 12. Molecular constants including those describing the hyperfine structures owing to the two halogen atoms were accurately determined for both species from the least-squares analysis of a total of 1475 distinct transition frequencies (of which 906 belong to the CH(2)I(35)Cl isotopologue). The two sets of rotational constants allowed us to derive an 60 structure of CH(2)ICl. Guided by a previous microwave study (9-35 GHz), the rotational spectrum of both chlorine isotopologues of chloroiodomethane in its vibrational and electronic ground state has been re-investigated in the microwave region and extended to the millimeter/submillimeter-wave region. Weak a-type transitions have been recorded by Fourier transform microwave spectroscopy below 20 GHz whilst strong b-type rotational transitions have been recorded between 15 and 646 GHz, corresponding to energy levels with J '' {= 108 and K(a)'' {= 12. Molecular constants including those describing the hyperfine structures owing to the two halogen atoms were accurately determined for both species from the least-squares analysis of a total of 1475 distinct transition frequencies (of which 906 belong to the CH(2)I(35)Cl isotopologue). The two sets of rotational constants allowed us to derive an 60 structure of CH(2)ICl. (en)
Title	Fourier-transform microwave and submillimeter-wave spectroscopy of chloroiodomethane, CH(2)ICl Fourier-transform microwave and submillimeter-wave spectroscopy of chloroiodomethane, CH(2)ICl (en)
skos:prefLabel	Fourier-transform microwave and submillimeter-wave spectroscopy of chloroiodomethane, CH(2)ICl Fourier-transform microwave and submillimeter-wave spectroscopy of chloroiodomethane, CH(2)ICl (en)
skos:notation	RIV/60461373:22340/11:43891819!RIV12-GA0-22340___
http://linked.open...avai/predkladatel	Fakulta chemicko-inženýrská
http://linked.open...avai/riv/aktivita	P
http://linked.open...avai/riv/aktivity	P(GPP206/10/P481)
http://linked.open...iv/cisloPeriodika	1
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Kania, Patrik
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoká škola chemicko-technologická v Praze / Fakulta chemicko-inženýrská
http://linked.open...dnocenehoVysledku	200258
http://linked.open...ai/riv/idVysledku	RIV/60461373:22340/11:43891819
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Hyperfine structure; Millimeter-wave spectroscopy; Fourier-transform spectroscopy; CH(2)ICl (en)
http://linked.open.../riv/klicoveSlovo	CH(2)ICl Fourier-transform spectroscopy Hyperfine structure Millimeter-wave spectroscopy
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[7D3C0876FCEC]
http://linked.open...i/riv/nazevZdroje	Journal of Molecular Spectroscopy
http://linked.open...in/vavai/riv/obor	CB
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...vavai/riv/projekt	Submillimeter wave spectroscopy of molecules cooled by adiabatic expansion: a tool for study of astrophysical and atmospherical molecules
http://linked.open...UplatneniVysledku	2011
http://linked.open...v/svazekPeriodika	270
http://linked.open...iv/tvurceVysledku	Bailleux, S. Duflot, D. Kania, Patrik Okabayashi, T. Ozeki, H. Sakai, S.
http://linked.open...ain/vavai/riv/wos	000296825000006
issn	0022-2852
number of pages	5 (xsd:int)
http://bibframe.org/vocab/doi	10.1016/j.jms.2011.09.002
http://localhost/t...ganizacniJednotka	22340
is http://linked.open...avai/riv/vysledek of	Fourier-transform microwave and submillimeter-wave spectroscopy of chloroiodomethane, CH(2)ICl Fourier-transform microwave and submillimeter-wave spectroscopy of chloroiodomethane, CH(2)ICl

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