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  • High-impact polypropylene (hiPP) is an important polymeric material with a wide range of applications particularly in automobiles industry. It is composed from porous isotactic polypropylene (iPP) matrix and from soft ethylene-propylene rubber (EPR) built in the pores of iPP matrix. Subsequent processing of hiPP involving melting changes the morphology of hiPP. Main application properties of hiPP material such as its toughness and impact resistance depend strongly on the size and distribution of EPR domains in the iPP matrix. We succeeded with high-resolution AFM imaging of EPR distribution in the cross-section of a whole hiPP particle and demonstrated the uneven distribution of EPR. By mapping of EPR distribution in particles we can understand the process of EPR rubber growth within the matrix of iPP as the initial porosity of iPP matrix is much smaller than the final content of EPR rubber. Morphology of hiPP is systematically characterized by a suitable set of morphology descriptors.
  • High-impact polypropylene (hiPP) is an important polymeric material with a wide range of applications particularly in automobiles industry. It is composed from porous isotactic polypropylene (iPP) matrix and from soft ethylene-propylene rubber (EPR) built in the pores of iPP matrix. Subsequent processing of hiPP involving melting changes the morphology of hiPP. Main application properties of hiPP material such as its toughness and impact resistance depend strongly on the size and distribution of EPR domains in the iPP matrix. We succeeded with high-resolution AFM imaging of EPR distribution in the cross-section of a whole hiPP particle and demonstrated the uneven distribution of EPR. By mapping of EPR distribution in particles we can understand the process of EPR rubber growth within the matrix of iPP as the initial porosity of iPP matrix is much smaller than the final content of EPR rubber. Morphology of hiPP is systematically characterized by a suitable set of morphology descriptors. (en)
Title
  • Morphology characterization and evolution of high-impact polypropylene
  • Morphology characterization and evolution of high-impact polypropylene (en)
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  • Morphology characterization and evolution of high-impact polypropylene
  • Morphology characterization and evolution of high-impact polypropylene (en)
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  • RIV/60461373:22340/10:00023228!RIV11-MPO-22340___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(FR-TI1/272), P(GD104/08/H055), S, Z(MSM6046137306)
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 272651
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  • RIV/60461373:22340/10:00023228
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • morphology; hetero-phase polymers; polypropylene; AFM (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [CE85451ABEC0]
http://linked.open...v/mistoKonaniAkce
  • Tatranské Matliare, Slovensko
http://linked.open...i/riv/mistoVydani
  • Bratislava
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  • Proceedings of the 37th International Conference of Slovak Society of Chemical Engineering, 2010
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http://linked.open...iv/tvurceVysledku
  • Gregor, Tomáš
  • Hajová, Hana
  • Kosek, Juraj
  • Smolná, Klára
http://linked.open...vavai/riv/typAkce
http://linked.open.../riv/zahajeniAkce
http://linked.open...n/vavai/riv/zamer
number of pages
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  • Slovak Society of Chemical Engineering
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  • 978-80-227-3290-1
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  • 22340
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