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  • This contribution presents a systematic study of evolution of heterophase morphologies as well as a systematic parametric study of impact resistance of morphologies of high impact polystyrene (HIPS). The model of the evolution of the so called salami morphology is based upon contra Fickian diffusion driven by the gradient of the chemical potential. The diffusion described by the gradient of chemical potential takes into the account the phase separation by mechanism of spinodal decompostion while parameter of interphase tension enables to describe the Ostwald rippening process. The resulting salami morphology can be characterized as follows: (i) polybutadiene (PB) particles with the size of several microns are distributed in the continuous polystyrene (PS) phase, and (ii) PB particles contain irregular sub-micron inclusions of PS
  • This contribution presents a systematic study of evolution of heterophase morphologies as well as a systematic parametric study of impact resistance of morphologies of high impact polystyrene (HIPS). The model of the evolution of the so called salami morphology is based upon contra Fickian diffusion driven by the gradient of the chemical potential. The diffusion described by the gradient of chemical potential takes into the account the phase separation by mechanism of spinodal decompostion while parameter of interphase tension enables to describe the Ostwald rippening process. The resulting salami morphology can be characterized as follows: (i) polybutadiene (PB) particles with the size of several microns are distributed in the continuous polystyrene (PS) phase, and (ii) PB particles contain irregular sub-micron inclusions of PS (en)
Title
  • Evolution of hetero-phase structure of high-impact polystyrene
  • Evolution of hetero-phase structure of high-impact polystyrene (en)
skos:prefLabel
  • Evolution of hetero-phase structure of high-impact polystyrene
  • Evolution of hetero-phase structure of high-impact polystyrene (en)
skos:notation
  • RIV/60461373:22340/09:00022487!RIV10-GA0-22340___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(FT-TA3/110), P(GA104/07/1127)
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 313977
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  • RIV/60461373:22340/09:00022487
http://linked.open...riv/jazykVysledku
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  • spinodal decomposition; high-impact polystyrene (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [8BC00D44C343]
http://linked.open...v/mistoKonaniAkce
  • Tatranské Matliare
http://linked.open...i/riv/mistoVydani
  • Bratislava
http://linked.open...i/riv/nazevZdroje
  • Proceedings of 36th International Conference of Slovak Society of Chemical Engineering
http://linked.open...in/vavai/riv/obor
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  • Gregor, Tomáš
  • Grof, Zdeněk
  • Kosek, Juraj
  • Vonka, Michal
  • Šeda, Libor
  • Klejch, Martin
http://linked.open...vavai/riv/typAkce
http://linked.open.../riv/zahajeniAkce
number of pages
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  • Slovenská technická univerzita v Bratislave
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  • 978-80-227-3072-3
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  • 22340
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