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  • The objective of this study is the transport of low molecular weight penetrants, such as ethylene, propylene and 1-hexene, in compact polyethylene (PE) or polypropylene (PP). Gravimetric sorption/desorption measurements were conducted in order to obtain transport characteristics as the time-dependence of the mass of sorbed species. Sorption and desorption characteristics were measured as responses to small and large pressure steps of penetrants. Small pressure steps covered the pressure range of interest and obtained transport characteristics provided the information about the concentration dependence of penetrant diffusivity in polymer. Penetrant diffusivities in compact polyolefin films, particles or threads were estimated by means of the simple model based on Fick?s diffusion. We provide short motivation for our study from the point of view of fundamental understanding of the problem. Moreover, we discuss current state-of-the-art of this problematic and explain the sources of large discrepancies be
  • The objective of this study is the transport of low molecular weight penetrants, such as ethylene, propylene and 1-hexene, in compact polyethylene (PE) or polypropylene (PP). Gravimetric sorption/desorption measurements were conducted in order to obtain transport characteristics as the time-dependence of the mass of sorbed species. Sorption and desorption characteristics were measured as responses to small and large pressure steps of penetrants. Small pressure steps covered the pressure range of interest and obtained transport characteristics provided the information about the concentration dependence of penetrant diffusivity in polymer. Penetrant diffusivities in compact polyolefin films, particles or threads were estimated by means of the simple model based on Fick?s diffusion. We provide short motivation for our study from the point of view of fundamental understanding of the problem. Moreover, we discuss current state-of-the-art of this problematic and explain the sources of large discrepancies be (en)
Title
  • Diffusion of monomers in polyethylene
  • Diffusion of monomers in polyethylene (en)
skos:prefLabel
  • Diffusion of monomers in polyethylene
  • Diffusion of monomers in polyethylene (en)
skos:notation
  • RIV/60461373:22340/09:00021975!RIV10-MSM-22340___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA104/07/1127), Z(MSM6046137306)
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 310527
http://linked.open...ai/riv/idVysledku
  • RIV/60461373:22340/09:00021975
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • sorption equilibria; diffusion in polymers; polyolefins; pressure decay (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [BA72AE13AB2A]
http://linked.open...v/mistoKonaniAkce
  • Srní, Šumava
http://linked.open...i/riv/mistoVydani
  • Praha
http://linked.open...i/riv/nazevZdroje
  • CHISA 2009
http://linked.open...in/vavai/riv/obor
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http://linked.open...vavai/riv/projekt
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http://linked.open...iv/tvurceVysledku
  • Gregor, Tomáš
  • Kosek, Juraj
  • Bobák, Marek
  • Holeček, Oldřich
  • Pecháčková, Lucie
http://linked.open...vavai/riv/typAkce
http://linked.open.../riv/zahajeniAkce
http://linked.open...n/vavai/riv/zamer
number of pages
http://purl.org/ne...btex#hasPublisher
  • Česká společnost chemického inženýrství
https://schema.org/isbn
  • 978-80-86059-51-8
http://localhost/t...ganizacniJednotka
  • 22340
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