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  • A method of numerical calculation of the fourth virial coefficients of the mixture of additive hard spheres is proposed. The results are compared with an exact analytical formula for the fourth partial virial coefficient B-4([1]) (i.e., three spheres of diameters sigma(1) and one sphere of diameter sigma(2)) and a semiempirical expression for B-4([2]) (i.e., two spheres of each kind). It is shown that the first formula is nonanalytic and the implication to the equations of state for hard-sphere mixtures is discussed.
  • A method of numerical calculation of the fourth virial coefficients of the mixture of additive hard spheres is proposed. The results are compared with an exact analytical formula for the fourth partial virial coefficient B-4([1]) (i.e., three spheres of diameters sigma(1) and one sphere of diameter sigma(2)) and a semiempirical expression for B-4([2]) (i.e., two spheres of each kind). It is shown that the first formula is nonanalytic and the implication to the equations of state for hard-sphere mixtures is discussed. (en)
Title
  • Analytical expressions for the fourth virial coefficient of a hard-sphere mixture
  • Analytical expressions for the fourth virial coefficient of a hard-sphere mixture (en)
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  • Analytical expressions for the fourth virial coefficient of a hard-sphere mixture
  • Analytical expressions for the fourth virial coefficient of a hard-sphere mixture (en)
skos:notation
  • RIV/60461373:22340/09:00021871!RIV10-MSM-22340___
http://linked.open...avai/riv/aktivita
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  • Z(MSM6046137307)
http://linked.open...iv/cisloPeriodika
  • 5
http://linked.open...vai/riv/dodaniDat
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  • 302994
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  • RIV/60461373:22340/09:00021871
http://linked.open...riv/jazykVysledku
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  • thermodynamics; virial equation; hard-spheres mixture (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [CD9E70474B1C]
http://linked.open...i/riv/nazevZdroje
  • Physical Review E
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 80
http://linked.open...iv/tvurceVysledku
  • Kolafa, Jiří
  • Labík, Stanislav
http://linked.open...ain/vavai/riv/wos
  • 000272309500028
http://linked.open...n/vavai/riv/zamer
issn
  • 1539-3755
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  • 22340
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