Attributes | Values |
---|
rdf:type
| |
Description
| - Distribuce vzduch-voda nižších N-methylovaných amidů mastných kyselin (N-methylformamid, N-methylacetamid, N,N-dimethylformamid, a N,N-dimethylacetamid) byla sledována při několika teplotách v intervalu od 333 do 373 K pomocí vhodných experimentálních technik: komparativní ebuliometrie, diferenciální destilace a metody rovnovážného cirkulačního přístroje. Výsledky jsou prezentovány ve formě limitních aktivitních koeficientů, konstant Henryho zákona a rozdělovacích koeficientů vzduch-voda. Pro každý amid zde prezentovaná data spolu s literárními údaji o měření rovnováhy kapalina-pára byly kombinovány s existujícími kalorimetrickými daty příslušných termických vlastností a simultánně korelovány vhodnou modelovou rovnicí. Během celého zpracování byla snaha minimalizovat vliv neurčitostí tlaků nasycených par čistých amidů při nízkých teplotách. Byly stanoveny doporučené termodynamicky konzistentní teplotní závislosti charakteristických veličin distribuce vzduch-voda, které dovolují jejich spolehlivou extr (cs)
- Air-water partitioning of lower N-methylated fatty acid amides (N-methylformamide, N-methylacetamide, N,N-dimethylformamide, and N,N-dimethylacetamide) was examined at several temperatures in the range from (333 to 373) K employing comparative ebulliometry, differential distillation, and the method of circulation still as suitable experimental techniques. Results are reported in the form of limiting (infinite dilution) relative volatility, limiting activity coefficient, Henry?s law constant, and air-water partition coefficient. For each amide, the present air-water partitioning data and some other relevant VLE measurements from the literature were combined with existing calorimetric data on respective derivative thermal properties and correlated simultaneously by a suitable model equation. In the entire treatment, precautions were taken to minimize the effect of uncertain vapor pressures of pure amides at lower temperatures. Recommended thermodynamically consistent temperature dependences of the air-w
- Air-water partitioning of lower N-methylated fatty acid amides (N-methylformamide, N-methylacetamide, N,N-dimethylformamide, and N,N-dimethylacetamide) was examined at several temperatures in the range from (333 to 373) K employing comparative ebulliometry, differential distillation, and the method of circulation still as suitable experimental techniques. Results are reported in the form of limiting (infinite dilution) relative volatility, limiting activity coefficient, Henry?s law constant, and air-water partition coefficient. For each amide, the present air-water partitioning data and some other relevant VLE measurements from the literature were combined with existing calorimetric data on respective derivative thermal properties and correlated simultaneously by a suitable model equation. In the entire treatment, precautions were taken to minimize the effect of uncertain vapor pressures of pure amides at lower temperatures. Recommended thermodynamically consistent temperature dependences of the air-w (en)
|
Title
| - Temperature Dependence of Air-Water Partitioning of N-Methylated (C1 and C2) Fatty Acid Amides
- Teplotní závislost distribuce N-methylovaných (C1 a C2) amidů mastných kyselin mezi vzduch a vodu (cs)
- Temperature Dependence of Air-Water Partitioning of N-Methylated (C1 and C2) Fatty Acid Amides (en)
|
skos:prefLabel
| - Temperature Dependence of Air-Water Partitioning of N-Methylated (C1 and C2) Fatty Acid Amides
- Teplotní závislost distribuce N-methylovaných (C1 a C2) amidů mastných kyselin mezi vzduch a vodu (cs)
- Temperature Dependence of Air-Water Partitioning of N-Methylated (C1 and C2) Fatty Acid Amides (en)
|
skos:notation
| - RIV/60461373:22340/08:00020684!RIV09-MSM-22340___
|
http://linked.open...avai/riv/aktivita
| |
http://linked.open...avai/riv/aktivity
| |
http://linked.open...iv/cisloPeriodika
| |
http://linked.open...vai/riv/dodaniDat
| |
http://linked.open...aciTvurceVysledku
| |
http://linked.open.../riv/druhVysledku
| |
http://linked.open...iv/duvernostUdaju
| |
http://linked.open...titaPredkladatele
| |
http://linked.open...dnocenehoVysledku
| |
http://linked.open...ai/riv/idVysledku
| - RIV/60461373:22340/08:00020684
|
http://linked.open...riv/jazykVysledku
| |
http://linked.open.../riv/klicovaSlova
| - Limiting activity coefficient; Henry`s law constant; Air-water partitioning; N-Methylated fatty acid amides; temperature dependence (en)
|
http://linked.open.../riv/klicoveSlovo
| |
http://linked.open...odStatuVydavatele
| - US - Spojené státy americké
|
http://linked.open...ontrolniKodProRIV
| |
http://linked.open...i/riv/nazevZdroje
| - Journal of Chemical Engineering Data
|
http://linked.open...in/vavai/riv/obor
| |
http://linked.open...ichTvurcuVysledku
| |
http://linked.open...cetTvurcuVysledku
| |
http://linked.open...UplatneniVysledku
| |
http://linked.open...v/svazekPeriodika
| |
http://linked.open...iv/tvurceVysledku
| - Dohnal, Vladimír
- Bernauer, Milan
|
http://linked.open...n/vavai/riv/zamer
| |
issn
| |
number of pages
| |
http://localhost/t...ganizacniJednotka
| |
is http://linked.open...avai/riv/vysledek
of | |