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Description
  • Byly studovány efektivní difúzní koeficienty pomocí chromatografické metody v SPSC koloně (nosný plyn: N2; stopovací plyny: He, Ar). Kolona byla naplněna kousky monolitu. Disperze signálu způsobená vedlejšími efekty byla odstraněna pomocí konvoluce odezvy pro 2 délky kolony. Měření byla provedena jak pro samotný keramický nosič, tak pro nosič pokrytý katalytickou vrstvou. Efektivní difúzní koeficienty pro dva páry nosný plyn - stopovací látka byly získány pomocí optimalizace parametrů elučních píků v časové doméně. Střední transportní parametry byly vyčísleny pro oba typy částic. Obdržené střední hodnoty poloměrů transportních pórů jsou v dobré shodě s distribucí poloměrů pórů získanými pomocí rtuťové porosimetre. (cs)
  • The effective diffusivity in the pores of catalytic monolith was studied in single pellet-string columns (SPSC) by chromatographic technique (carrier-gas: N2; tracer-gases: He, Ar). The column was packed with small monolith particles (slab geometry). Dispersion due to extra column effects was eliminated via convolution of responses for two column lengths. The measurements were done for both cordierite support and cordierite support with alumina based washcoat. The effective diffusion coefficients for two tracer-carrier pairs were evaluated by fitting column response (chromatographic) peaks in time domain. Mean transport parameters were evaluated for both types of porous particles. Obtained mean transport pore radii are in reasonable agreement with pore size distribution from mercury porosimetry.
  • The effective diffusivity in the pores of catalytic monolith was studied in single pellet-string columns (SPSC) by chromatographic technique (carrier-gas: N2; tracer-gases: He, Ar). The column was packed with small monolith particles (slab geometry). Dispersion due to extra column effects was eliminated via convolution of responses for two column lengths. The measurements were done for both cordierite support and cordierite support with alumina based washcoat. The effective diffusion coefficients for two tracer-carrier pairs were evaluated by fitting column response (chromatographic) peaks in time domain. Mean transport parameters were evaluated for both types of porous particles. Obtained mean transport pore radii are in reasonable agreement with pore size distribution from mercury porosimetry. (en)
Title
  • MEASUREMENT OF EFFECTIVE DIFFUSIVITY IN CATALYST-COATED MONOLITH BY CHROMATOGRAPHIC METHOD
  • MEASUREMENT OF EFFECTIVE DIFFUSIVITY IN CATALYST-COATED MONOLITH BY CHROMATOGRAPHIC METHOD (en)
  • Měření efektivních difúzních koeficientů v katalytickém monolitu pomocí chromatografické metody (cs)
skos:prefLabel
  • MEASUREMENT OF EFFECTIVE DIFFUSIVITY IN CATALYST-COATED MONOLITH BY CHROMATOGRAPHIC METHOD
  • MEASUREMENT OF EFFECTIVE DIFFUSIVITY IN CATALYST-COATED MONOLITH BY CHROMATOGRAPHIC METHOD (en)
  • Měření efektivních difúzních koeficientů v katalytickém monolitu pomocí chromatografické metody (cs)
skos:notation
  • RIV/60461373:22340/05:00014575!RIV06-GA0-22340___
http://linked.open.../vavai/riv/strany
  • ID159/1-ID159/10
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA104/05/2616), Z(MSM6046137306)
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 529190
http://linked.open...ai/riv/idVysledku
  • RIV/60461373:22340/05:00014575
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Catalyst monolith; Diffusion; Mass transfer; Single pellet-string column (SPSC); Transport processes; Chromatographic method (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [247A7687CF3E]
http://linked.open...v/mistoKonaniAkce
  • Tatrianské Matliare, Slovensko
http://linked.open...i/riv/mistoVydani
  • Bratislava
http://linked.open...i/riv/nazevZdroje
  • Proc. of 32th International Conference of Slovak Society of Chemical Engineering.
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...iv/tvurceVysledku
  • Schneider, Petr
  • Marek, Miloš
  • Starý, Tomáš
  • Šolcová, Olina
http://linked.open...vavai/riv/typAkce
http://linked.open.../riv/zahajeniAkce
http://linked.open...n/vavai/riv/zamer
number of pages
http://purl.org/ne...btex#hasPublisher
  • Slovenská technická univerzita v Bratislave
https://schema.org/isbn
  • 80-227-2224-3
http://localhost/t...ganizacniJednotka
  • 22340
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