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Description
| - Byly studovány efektivní difúzní koeficienty pomocí chromatografické metody v SPSC koloně (nosný plyn: N2; stopovací plyny: He, Ar). Kolona byla naplněna kousky monolitu. Disperze signálu způsobená vedlejšími efekty byla odstraněna pomocí konvoluce odezvy pro 2 délky kolony. Měření byla provedena jak pro samotný keramický nosič, tak pro nosič pokrytý katalytickou vrstvou. Efektivní difúzní koeficienty pro dva páry nosný plyn - stopovací látka byly získány pomocí optimalizace parametrů elučních píků v časové doméně. Střední transportní parametry byly vyčísleny pro oba typy částic. Obdržené střední hodnoty poloměrů transportních pórů jsou v dobré shodě s distribucí poloměrů pórů získanými pomocí rtuťové porosimetre. (cs)
- The effective diffusivity in the pores of catalytic monolith was studied in single pellet-string columns (SPSC) by chromatographic technique (carrier-gas: N2; tracer-gases: He, Ar). The column was packed with small monolith particles (slab geometry). Dispersion due to extra column effects was eliminated via convolution of responses for two column lengths. The measurements were done for both cordierite support and cordierite support with alumina based washcoat. The effective diffusion coefficients for two tracer-carrier pairs were evaluated by fitting column response (chromatographic) peaks in time domain. Mean transport parameters were evaluated for both types of porous particles. Obtained mean transport pore radii are in reasonable agreement with pore size distribution from mercury porosimetry.
- The effective diffusivity in the pores of catalytic monolith was studied in single pellet-string columns (SPSC) by chromatographic technique (carrier-gas: N2; tracer-gases: He, Ar). The column was packed with small monolith particles (slab geometry). Dispersion due to extra column effects was eliminated via convolution of responses for two column lengths. The measurements were done for both cordierite support and cordierite support with alumina based washcoat. The effective diffusion coefficients for two tracer-carrier pairs were evaluated by fitting column response (chromatographic) peaks in time domain. Mean transport parameters were evaluated for both types of porous particles. Obtained mean transport pore radii are in reasonable agreement with pore size distribution from mercury porosimetry. (en)
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Title
| - MEASUREMENT OF EFFECTIVE DIFFUSIVITY IN CATALYST-COATED MONOLITH BY CHROMATOGRAPHIC METHOD
- MEASUREMENT OF EFFECTIVE DIFFUSIVITY IN CATALYST-COATED MONOLITH BY CHROMATOGRAPHIC METHOD (en)
- Měření efektivních difúzních koeficientů v katalytickém monolitu pomocí chromatografické metody (cs)
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skos:prefLabel
| - MEASUREMENT OF EFFECTIVE DIFFUSIVITY IN CATALYST-COATED MONOLITH BY CHROMATOGRAPHIC METHOD
- MEASUREMENT OF EFFECTIVE DIFFUSIVITY IN CATALYST-COATED MONOLITH BY CHROMATOGRAPHIC METHOD (en)
- Měření efektivních difúzních koeficientů v katalytickém monolitu pomocí chromatografické metody (cs)
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skos:notation
| - RIV/60461373:22340/05:00014575!RIV06-GA0-22340___
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http://linked.open.../vavai/riv/strany
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(GA104/05/2616), Z(MSM6046137306)
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/60461373:22340/05:00014575
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - Catalyst monolith; Diffusion; Mass transfer; Single pellet-string column (SPSC); Transport processes; Chromatographic method (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...ontrolniKodProRIV
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http://linked.open...v/mistoKonaniAkce
| - Tatrianské Matliare, Slovensko
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http://linked.open...i/riv/mistoVydani
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http://linked.open...i/riv/nazevZdroje
| - Proc. of 32th International Conference of Slovak Society of Chemical Engineering.
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...iv/tvurceVysledku
| - Schneider, Petr
- Marek, Miloš
- Starý, Tomáš
- Šolcová, Olina
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http://linked.open...vavai/riv/typAkce
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http://linked.open.../riv/zahajeniAkce
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http://linked.open...n/vavai/riv/zamer
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number of pages
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http://purl.org/ne...btex#hasPublisher
| - Slovenská technická univerzita v Bratislave
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https://schema.org/isbn
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http://localhost/t...ganizacniJednotka
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is http://linked.open...avai/riv/vysledek
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