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  • The electrolyte diode is studied both experimentally and by means of mathematical modelling. Simulation results show that the use of assumptions common on a macro scale (such as the local electroneutrality assumption, instantaneous local dissociation and recombination equilibria), on a micro-scale may lead to results inconsistent with reality. Experimental research is devoted to (i) studies of diode behaviour in different experimental arrangements and (ii) development of observation techniques suitable for direct evidence of concentration profiles inside the microsystem. Both fluorescence and absorbance detection methods have been succesfully tested.
  • The electrolyte diode is studied both experimentally and by means of mathematical modelling. Simulation results show that the use of assumptions common on a macro scale (such as the local electroneutrality assumption, instantaneous local dissociation and recombination equilibria), on a micro-scale may lead to results inconsistent with reality. Experimental research is devoted to (i) studies of diode behaviour in different experimental arrangements and (ii) development of observation techniques suitable for direct evidence of concentration profiles inside the microsystem. Both fluorescence and absorbance detection methods have been succesfully tested. (en)
  • Příspěvek shrnuje výsledky studia elektrolytické diody jak experimentálního, tak i pomocí matematického modelování. Výsledky numerických simulací ukazují, že některé předpoklady běžně používané v makroměřítku (např. lokální elektroneutralita, okamžité disociační rovnováhy) v mikroměřítku mohou vést k fyzikálně nesprávným výsledkům. Experimentální výzkum je zaměřen na studium chování elektrolytické diody v různém experimentálním uspořádání a na vývoj technik pro pozorování změn koncentračních polí uvnitř systému. Úspěšně byly testovány metodiky vizualizace pomocí absorbančních a fluorescenčních indikátorů. (cs)
Title
  • Elektrolytická dioda jako teoretický a experimentální systém pro studium transportních a reakčních jevů v mikro- a nano-strukturovaných systémech (cs)
  • Electrolyte diode as theoretical and experimental system for studies of transport and reaction phenomena in micro- and nanostructurized systems
  • Electrolyte diode as theoretical and experimental system for studies of transport and reaction phenomena in micro- and nanostructurized systems (en)
skos:prefLabel
  • Elektrolytická dioda jako teoretický a experimentální systém pro studium transportních a reakčních jevů v mikro- a nano-strukturovaných systémech (cs)
  • Electrolyte diode as theoretical and experimental system for studies of transport and reaction phenomena in micro- and nanostructurized systems
  • Electrolyte diode as theoretical and experimental system for studies of transport and reaction phenomena in micro- and nanostructurized systems (en)
skos:notation
  • RIV/60461373:22340/04:00013200!RIV/2005/GA0/223405/N
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  • 100(1-10)
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  • P(GP104/03/D005), Z(MSM 223400007)
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  • 562534
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  • RIV/60461373:22340/04:00013200
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  • Electrolyte diode;Microsystems;Acid-base equilibria;Non-linear phenomena (en)
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  • [9FE5255195D4]
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  • Tatranské Matliare
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  • Bratislava
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  • Proc. of 31th International Conference of Slovak Society of Chemical Engineering, Tatranské Matliare 24.- 28.5.2004, CD-ROM
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  • Slouka, Zdeněk
  • Šnita, Dalimil
  • Lindner, Jiří
  • Postler, Tomáš
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number of pages
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  • Slovenská technická univerzita v Bratislave
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  • 80-227-2052-6
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  • 22340
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