About: Group contributions for an estimation of partial molar volumes at infinite dilution for aqueous organic solutes at extended ranged of temperature and pressure.

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About: Group contributions for an estimation of partial molar volumes at infinite dilution for aqueous organic solutes at extended ranged of temperature and pressure. Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Experimental data on the partial molar volume at infinite dilution for two groups of organic solutes (derivatives of benzene and aliphatic hydroxyl derivatives) measured using a vibrating-tube densimeter in the temperature and pressure ranges 298 - 573 Kand 0.1 - 30 MPa were summarized. A function of temperature and pressure was proposed for smoothing the data. Smoothed values of partial molar volume as a function of temperature and pressure are employed for the evaluation of group and structural contr ibutions. The contributions obtained for particular selected T,p pairs were smoothed and used to estimate the partial molar volumes at infinite dilution of various solutes. Average deviation between partial molar volumes calculated from the contributionsand the experimental data employed for the evaluation of the contributions was less than 1 cm3/mol. Predictions of partial molar volumes of solutes not included in the evaluation of the contributions were performed and compared with available experiment Experimental data on the partial molar volume at infinite dilution for two groups of organic solutes (derivatives of benzene and aliphatic hydroxyl derivatives) measured using a vibrating-tube densimeter in the temperature and pressure ranges 298 - 573 Kand 0.1 - 30 MPa were summarized. A function of temperature and pressure was proposed for smoothing the data. Smoothed values of partial molar volume as a function of temperature and pressure are employed for the evaluation of group and structural contr ibutions. The contributions obtained for particular selected T,p pairs were smoothed and used to estimate the partial molar volumes at infinite dilution of various solutes. Average deviation between partial molar volumes calculated from the contributionsand the experimental data employed for the evaluation of the contributions was less than 1 cm3/mol. Predictions of partial molar volumes of solutes not included in the evaluation of the contributions were performed and compared with available experiment (en)
Title	Group contributions for an estimation of partial molar volumes at infinite dilution for aqueous organic solutes at extended ranged of temperature and pressure. Group contributions for an estimation of partial molar volumes at infinite dilution for aqueous organic solutes at extended ranged of temperature and pressure. (en)
skos:prefLabel	Group contributions for an estimation of partial molar volumes at infinite dilution for aqueous organic solutes at extended ranged of temperature and pressure. Group contributions for an estimation of partial molar volumes at infinite dilution for aqueous organic solutes at extended ranged of temperature and pressure. (en)
skos:notation	RIV/60461373:22340/03:00007419!RIV/2004/MSM/223404/N
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(MSM 223400008)
http://linked.open...vai/riv/dodaniDat	2004
http://linked.open...aciTvurceVysledku	Hnědkovský, Lubomír Cibulka, Ivan
http://linked.open.../riv/druhVysledku	A(V) - Audiovizuální tvorba se vzdáleným přístupem
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoká škola chemicko-technologická v Praze / Fakulta chemicko-inženýrská
http://linked.open...dnocenehoVysledku	608533
http://linked.open...ai/riv/idVysledku	RIV/60461373:22340/03:00007419
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	partial molar volume; dilute aqueous solutions; group contribution method; (en)
http://linked.open.../riv/klicoveSlovo	group contribution method partial molar volume dilute aqueous solutions
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http://linked.open...telVyzkumneZpravy	NIST/ASME
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http://linked.open...UplatneniVysledku	2003
http://linked.open...iv/tvurceVysledku	Cibulka, Ivan Hnědkovský, Lubomír
http://linked.open...rzeVyzkumneZpravy	neuveden
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