About: The complexation of the metal cations by galacturonic acid: A vibrational circular dichroism study

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About: The complexation of the metal cations by galacturonic acid: A vibrational circular dichroism study Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Solid complexes of D-galacturonic acid with copper(II), cobalt(II), nickel(II) and oxovanadium(IV) were synthesised by the treatment of aqueous solution of the acid with freshly prepared metal hydroxides followed by precipitation with 2-propanol. Vibrational absorption and circular dichroism spectra of these complexes as well as of free ligand were measured in D2O and Me2SO-d6 systems. These results confirm that uronic carboxylates in metal complexes may participate in the formation of optically active species. Solid complexes of D-galacturonic acid with copper(II), cobalt(II), nickel(II) and oxovanadium(IV) were synthesised by the treatment of aqueous solution of the acid with freshly prepared metal hydroxides followed by precipitation with 2-propanol. Vibrational absorption and circular dichroism spectra of these complexes as well as of free ligand were measured in D2O and Me2SO-d6 systems. These results confirm that uronic carboxylates in metal complexes may participate in the formation of optically active species. (en)
Title	The complexation of the metal cations by galacturonic acid: A vibrational circular dichroism study The complexation of the metal cations by galacturonic acid: A vibrational circular dichroism study (en) The complexation of the metal cations by galacturonic acid: A vibrational circular dichroism study (cs)
skos:prefLabel	The complexation of the metal cations by galacturonic acid: A vibrational circular dichroism study The complexation of the metal cations by galacturonic acid: A vibrational circular dichroism study (en) The complexation of the metal cations by galacturonic acid: A vibrational circular dichroism study (cs)
skos:notation	RIV/60461373:22340/02:00006898!RIV/2004/GA0/223404/N
http://linked.open.../vavai/riv/strany	P20;P20
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/02/0328), Z(MSM 223400008)
http://linked.open...vai/riv/dodaniDat	2004
http://linked.open...aciTvurceVysledku	Čopíková, Jana Synytsya, Andriy Urbanová, Marie Setnička, Vladimír
http://linked.open.../riv/druhVysledku	D - Článek ve sborníku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoká škola chemicko-technologická v Praze / Fakulta chemicko-inženýrská
http://linked.open...dnocenehoVysledku	641419
http://linked.open...ai/riv/idVysledku	RIV/60461373:22340/02:00006898
http://linked.open...riv/jazykVysledku	cze - čeština
http://linked.open.../riv/klicovaSlova	Metal complexes; galacturonic acid; vibrational circular dichroism (en)
http://linked.open.../riv/klicoveSlovo	vibrational circular dichroism galacturonic acid Metal complexes
http://linked.open...ontrolniKodProRIV	[A760D7517D84]
http://linked.open...v/mistoKonaniAkce	Prague, Czech Republic
http://linked.open...i/riv/mistoVydani	Praha
http://linked.open...i/riv/nazevZdroje	CUKRBLIK 2002, Current Blycobiology, Chemistry and Biochemistry of Saccharides in Czechia
http://linked.open...in/vavai/riv/obor	CE
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	Chiroptical properties, conformation and dynamical behaviour of the middle sized oligopeptide having structural domains with different flexibility
http://linked.open...UplatneniVysledku	2002
http://linked.open...iv/tvurceVysledku	Čopíková, Jana Urbanová, Marie Setnička, Vladimír Sinica, Andrij
http://linked.open...vavai/riv/typAkce	WRD - Světová
http://linked.open.../riv/zahajeniAkce	2002-03-07 (xsd:date)
http://linked.open...n/vavai/riv/zamer	http://linked.opendata.cz/resource/domain/vavai/zamer/MSM%20223400008
number of pages	1 (xsd:int)
http://purl.org/ne...btex#hasPublisher	Institute of Microbiology
https://schema.org/isbn	80-86238-20-2
http://localhost/t...ganizacniJednotka	22340

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