About: Liquid + liquid equilibrium in the ternary systems water + ethanol + dialkyl phthalate (dimethyl, diethyl and dibutyl phthalate) at 298.15 K     Goto   Sponge   NotDistinct   Permalink

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  • Liquid + liquid equilibrium was determined for three ternary systems water + ethanol + dialkyl phthalates (dimethyl, diethyl and dibutyl phthalate) at 298.15 K. The turbidimetry titration method was used to obtain the binodal curves. Direct analytical methods were used to determine the composition of coexisting phases. The critical point composition was extrapolated from equilibrium data for each of the ternary systems using the Coolidge method. Excess enthalpy data were obtained for the system dimethylphthalate + ethanol at 298.15 K. These, along with ternary and literature binary data, allowed a thorough thermodynamic description of the system water + ethanol + dimethyl phthalate. The modified Wilson equation was employed to this purpose.
  • Liquid + liquid equilibrium was determined for three ternary systems water + ethanol + dialkyl phthalates (dimethyl, diethyl and dibutyl phthalate) at 298.15 K. The turbidimetry titration method was used to obtain the binodal curves. Direct analytical methods were used to determine the composition of coexisting phases. The critical point composition was extrapolated from equilibrium data for each of the ternary systems using the Coolidge method. Excess enthalpy data were obtained for the system dimethylphthalate + ethanol at 298.15 K. These, along with ternary and literature binary data, allowed a thorough thermodynamic description of the system water + ethanol + dimethyl phthalate. The modified Wilson equation was employed to this purpose. (en)
Title
  • Liquid + liquid equilibrium in the ternary systems water + ethanol + dialkyl phthalate (dimethyl, diethyl and dibutyl phthalate) at 298.15 K
  • Liquid + liquid equilibrium in the ternary systems water + ethanol + dialkyl phthalate (dimethyl, diethyl and dibutyl phthalate) at 298.15 K (en)
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  • Liquid + liquid equilibrium in the ternary systems water + ethanol + dialkyl phthalate (dimethyl, diethyl and dibutyl phthalate) at 298.15 K
  • Liquid + liquid equilibrium in the ternary systems water + ethanol + dialkyl phthalate (dimethyl, diethyl and dibutyl phthalate) at 298.15 K (en)
skos:notation
  • RIV/60461373:22340/01:00003924!RIV/2004/MSM/223404/N
http://linked.open.../vavai/riv/strany
  • 1605;1609
http://linked.open...avai/riv/aktivita
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  • Z(MSM 223400008)
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  • 6
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  • 685388
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  • RIV/60461373:22340/01:00003924
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  • Liquid + liquid equilibrium; phthalates; water; ethanol (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [AE62C7304E6D]
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  • Journal of Chemical and Engineering Data
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http://linked.open...v/svazekPeriodika
  • 46
http://linked.open...iv/tvurceVysledku
  • Novák, Josef
  • Řehák, Karel
  • Bendová, Magdalena
  • Matouš, Jaroslav
http://linked.open...n/vavai/riv/zamer
issn
  • 0021-9568
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  • 22340
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