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  • Reactions of isothiocyanates (ITCs) in the presence of amino compounds were studied. They led to colored structures via substituted 2-thiohydantoins. Low-molecular colorants isolated and characterized from the model systems were yellow to red diastereomeric dehydrodimers of 2-thiohydantoin derivatives that contain an acidic methylene group are formed in mixtures consisted of ITCs and amino acids with -methylene group in mild acidic to mild alkaline systems. The condensation products of the 2-thiohydantoins with reactive aromatic or heterocyclic carbaldehydes from the Maillard reaction, essential oils etc. comprise a heterogeneous group of mostly yellow colorants. Blue compounds of two types are structurally more complicated structures that arise from N-substituted amino acids and ITCs in alkaline media.
  • Reactions of isothiocyanates (ITCs) in the presence of amino compounds were studied. They led to colored structures via substituted 2-thiohydantoins. Low-molecular colorants isolated and characterized from the model systems were yellow to red diastereomeric dehydrodimers of 2-thiohydantoin derivatives that contain an acidic methylene group are formed in mixtures consisted of ITCs and amino acids with -methylene group in mild acidic to mild alkaline systems. The condensation products of the 2-thiohydantoins with reactive aromatic or heterocyclic carbaldehydes from the Maillard reaction, essential oils etc. comprise a heterogeneous group of mostly yellow colorants. Blue compounds of two types are structurally more complicated structures that arise from N-substituted amino acids and ITCs in alkaline media. (en)
Title
  • Advances in chemistry of isothiocyanate-derived colourants.
  • Advances in chemistry of isothiocyanate-derived colourants. (en)
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  • Advances in chemistry of isothiocyanate-derived colourants.
  • Advances in chemistry of isothiocyanate-derived colourants. (en)
skos:notation
  • RIV/60461373:22330/09:00022347!RIV10-MSM-22330___
http://linked.open...avai/riv/aktivita
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  • P(OC 122), Z(MSM6046137305)
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  • S
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  • 302058
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  • RIV/60461373:22330/09:00022347
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  • isothiocyanates; amino acids; 2-thiohydantoins; Maillard reaction (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CZ - Česká republika
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  • [CC4AF02C5F8B]
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  • Czech Journal of Food Science
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  • 27
http://linked.open...iv/tvurceVysledku
  • Cejpek, Karel
  • Velíšek, Jan
http://linked.open...ain/vavai/riv/wos
  • 000269005600064
http://linked.open...n/vavai/riv/zamer
issn
  • 1212-1800
number of pages
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  • 22330
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