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  • Precursors involved in the formation of pink and green-blue pigments generated during onion and garlic processing, respectively, have been studied. It has been confirmed that the formations of both pigments are of very similar natures, with (E)-S-(1-propenyl)cysteine sulfoxide (isoalliin) serving as the primary precursor. Upon disruption of the tissue, isoalliin and other S-alk(en)ylcysteine sulfoxides are enzymatically cleaved, yielding 1-propenyl-containing thiosulfinates [CH3CH=CHS(O)SR; R = methyl, allyl, propyl, 1-propenyl] among others. The latter compounds have been shown to subsequently react with amino acids to produce the pigments. Whereas the propyl, 1-propenyl, and methyl derivatives form pink, pink-red, and magenta compounds, those containing the allyl group give rise to blue products after reacting with glycine at pH 5.0. The role of other thiosulfinates [RS(O)SR'] (R, R' = methyl, allyl, propyl) and (Z)-thiopropanal S-oxide (the onion lachrymatory principle) in the formation o
  • Precursors involved in the formation of pink and green-blue pigments generated during onion and garlic processing, respectively, have been studied. It has been confirmed that the formations of both pigments are of very similar natures, with (E)-S-(1-propenyl)cysteine sulfoxide (isoalliin) serving as the primary precursor. Upon disruption of the tissue, isoalliin and other S-alk(en)ylcysteine sulfoxides are enzymatically cleaved, yielding 1-propenyl-containing thiosulfinates [CH3CH=CHS(O)SR; R = methyl, allyl, propyl, 1-propenyl] among others. The latter compounds have been shown to subsequently react with amino acids to produce the pigments. Whereas the propyl, 1-propenyl, and methyl derivatives form pink, pink-red, and magenta compounds, those containing the allyl group give rise to blue products after reacting with glycine at pH 5.0. The role of other thiosulfinates [RS(O)SR'] (R, R' = methyl, allyl, propyl) and (Z)-thiopropanal S-oxide (the onion lachrymatory principle) in the formation o (en)
  • Byly studovány prekurzory podílející se na tvorbě růžového a zelenomodrého zbarvení vznikajícího během zpracování cibule a česneku. Bylo zjištěno, že oba procesy jsou velmi podobného charakteru, přičemž klíčovým prekurzorem je (E)-S-(1-propenyl)cysteinsulfoxid (isoalliin). Při porušení rostlinného pletiva dochází k enzymovému rozkladu isoalliinu a dalších S-alk(en)ylcysteinsulfoxidů za tvorby 1-propenylthiosulfinátů [CH3CH=CHS(O)SR; R = methyl, allyl, propyl, 1-propenyl]. Tyto thiosulfináty následně reagují s aminokyselinami za vzniku barevných látek. Zatímco propyl, 1-propenyl a methylthiosulfináty tvoří růžové, červenorůžové popř. fialové sloučeniny, thiosulfináty obsahující allylovou skupinu generují modré látky při reakci s glycinem (pH 5,0). Byla též studována role dalších thiosulfinátů [RS(O)SR'] (R, R' = methyl, allyl, propyl) a (Z)-thiopropanal-S-oxidu. (cs)
Title
  • Allium Discoloration: Precursors Involved in Onion Pinking and Garlic Greening
  • Allium Discoloration: Precursors Involved in Onion Pinking and Garlic Greening (en)
  • Allium zbarvení: Prekurzory podílející se na růžovění cibule a zelenění česneku (cs)
skos:prefLabel
  • Allium Discoloration: Precursors Involved in Onion Pinking and Garlic Greening
  • Allium Discoloration: Precursors Involved in Onion Pinking and Garlic Greening (en)
  • Allium zbarvení: Prekurzory podílející se na růžovění cibule a zelenění česneku (cs)
skos:notation
  • RIV/60461373:22330/04:00019604!RIV09-GA0-22330___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GP525/03/P007), P(OC 919.10)
http://linked.open...iv/cisloPeriodika
  • 54
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 553906
http://linked.open...ai/riv/idVysledku
  • RIV/60461373:22330/04:00019604
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Allium; onion; leek; garlic; pinking; reddening; greening; discoloration; thiosulfinate; isoalliin (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [0E7FB28FAC1B]
http://linked.open...i/riv/nazevZdroje
  • Journal of Agricultural and Food Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...iv/tvurceVysledku
  • Kubec, Roman
  • Velíšek, Jan
  • Hrbáčková, M.
  • Musah, R.A..
http://linked.open...ain/vavai/riv/wos
  • 000223137000026
issn
  • 0021-8561
number of pages
http://localhost/t...ganizacniJednotka
  • 22330
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