About: A novel synthesis of parent resorc[4]arene and its partial alkyl ethers     Goto   Sponge   NotDistinct   Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

AttributesValues
rdf:type
Description
  • Treatment of 2,4-diisopropoxybenzyl alcohol with chlorotrimethylsilane in acetonitrile at room temperature for 1 h afforded a novel crystalline resorc[4]arene octaisopropyl ether in 96% yield. Protecting groups were cleaved by boron trichloride in dichloromethane within 30 min and the parent resorc[4]arene was isolated by flash chromatography in 76% yield. The outcome of the deprotection step was dependent on the conditions used as it is exemplified bya preparation of resorc[4]arene heptaisopropyl ether.
  • Treatment of 2,4-diisopropoxybenzyl alcohol with chlorotrimethylsilane in acetonitrile at room temperature for 1 h afforded a novel crystalline resorc[4]arene octaisopropyl ether in 96% yield. Protecting groups were cleaved by boron trichloride in dichloromethane within 30 min and the parent resorc[4]arene was isolated by flash chromatography in 76% yield. The outcome of the deprotection step was dependent on the conditions used as it is exemplified bya preparation of resorc[4]arene heptaisopropyl ether. (en)
  • 2,4-Diisopropoxybenzylalkohol poskytl působením trimethylchlorsilanu v acetonitrilu během 1 hodiny za pokojové teploty nový krystalický resorc[4]aren oktaisopropylether ve výtěžku 96 %. Chránicí skupiny byly odstraněna chloridem boritým a resorc[4]aren byl isolován ve výtěžku 76 %. Za různých podmínek byly získány parciálně alkylovaný resorc[4]aren. (cs)
Title
  • Nová synthesa resorc[4]arenu a jeho parciálních alkyletherů. (cs)
  • A novel synthesis of parent resorc[4]arene and its partial alkyl ethers
  • A novel synthesis of parent resorc[4]arene and its partial alkyl ethers (en)
skos:prefLabel
  • Nová synthesa resorc[4]arenu a jeho parciálních alkyletherů. (cs)
  • A novel synthesis of parent resorc[4]arene and its partial alkyl ethers
  • A novel synthesis of parent resorc[4]arene and its partial alkyl ethers (en)
skos:notation
  • RIV/60461373:22330/04:00012725!RIV/2005/MSM/223305/N
http://linked.open.../vavai/riv/strany
  • 2043-2046
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM 223300006)
http://linked.open...iv/cisloPeriodika
  • 45
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 553091
http://linked.open...ai/riv/idVysledku
  • RIV/60461373:22330/04:00012725
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Resorc[4]arene;2,4-Diisopropoxybenzyl alcohol;Lewis acid;Conformation;Partially alkylated resorc[4]arene (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • BE - Belgické království
http://linked.open...ontrolniKodProRIV
  • [A6A0E811973B]
http://linked.open...i/riv/nazevZdroje
  • Tetrahedron Letters
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • neuveden
http://linked.open...iv/tvurceVysledku
  • Šmidrkal, Jan
  • Dvořáková, Hana
  • Štursa, Jan
  • Moravcová, Jitka
  • Petříčková, Hana
http://linked.open...n/vavai/riv/zamer
issn
  • 0040-4039
number of pages
http://localhost/t...ganizacniJednotka
  • 22330
Faceted Search & Find service v1.16.118 as of Jun 21 2024


Alternative Linked Data Documents: ODE     Content Formats:   [cxml] [csv]     RDF   [text] [turtle] [ld+json] [rdf+json] [rdf+xml]     ODATA   [atom+xml] [odata+json]     Microdata   [microdata+json] [html]    About   
This material is Open Knowledge   W3C Semantic Web Technology [RDF Data] Valid XHTML + RDFa
OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 58 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software